“…The starting material, the aldehyde 4-formylphenyl(4-methoxyphenyl) acetate, was prepared as previously described. 22 The macrocycle of H 2 TMAPP was synthesized and puried according to the procedures described by Lindsey et al, 23 and cobalt was inserted into the porphyrin molecule by the dimethylformamide method 24,25 (Scheme S1 †).…”
In this work, a new porphyrin, 5,10,15,20-tetrakis{4-[((4-methoxyphenyl)acetyl)oxy]phenyl}porphyrin (H2TMAPP) (1), and its cobalt complex [CoII(TMAPP)] (2) were synthesized in good and quantitative yields, respectively.
“…The starting material, the aldehyde 4-formylphenyl(4-methoxyphenyl) acetate, was prepared as previously described. 22 The macrocycle of H 2 TMAPP was synthesized and puried according to the procedures described by Lindsey et al, 23 and cobalt was inserted into the porphyrin molecule by the dimethylformamide method 24,25 (Scheme S1 †).…”
In this work, a new porphyrin, 5,10,15,20-tetrakis{4-[((4-methoxyphenyl)acetyl)oxy]phenyl}porphyrin (H2TMAPP) (1), and its cobalt complex [CoII(TMAPP)] (2) were synthesized in good and quantitative yields, respectively.
A new class of bowl-shaped supramolecular liquid crystals (LCs) is described derived from calix[4]arene substituted with 1,3,4-thiadiazole derivatives, inbuilt with Schiff base and ester on the lower rim and with an azo group on the upper rim with an alkyl side chain (–OC3H7, –OC8H17).
A new family of supramolecular liquid crystalline compounds with a calix[4]arene core and two linking group appended on four-side exhibiting wide range of hexagonal columnar phase have been synthesized and...
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