Synthesis and optimization of NASICON-type Li3V2(PO4)3 by adipic acid-mediated solid-state approach

Effect of Carbon Matrix Dimensions on the Electrochemical Properties of Na3V2(PO4)3 Nanograins for High‐Performance Symmetric Sodium‐Ion Batteries

“…The cyclic performances of the Na 3 V 2 (PO 4 ) 3 /AC, Na 3 V 2 (PO 4 ) 3 /CNT and Na 3 V 2 (PO 4 ) 3 /graphite electrodes in 2.3 to 3.9 V at 5 C rate are demonstrated in Figure 3 c. The initial discharge capacity of Na 3 V 2 (PO 4 ) 3 /AC cathode is up to 100.6 mAh g −1 , closer to the theoretical capacity than the other two samples. [ 57 ] This is further testifi ed by the discharge profi le of Na 3 V 2 (PO 4 ) 3 /AC at the rate of 0.1 C as indicated in Figure S5. After 200 cycles, the capacities of Na 3 V 2 (PO 4 ) 3 /AC, Na 3 V 2 (PO 4 ) 3 /CNT and Na 3 V 2 (PO 4 ) 3 /graphite cathodes decrease to 97.0, 56.3 and 40.8 mAh g −1 , corresponding to the capacity retention of 96.4%, 65.3% and 65.1% of their initial capacity, respectively.…”

The high electrochemical performance of Li 3 V 2 (PO 4 ) 3 supported by graphene and carbon-nanofibers for advanced Li-ion batteries

“…It is reported that the formation of polymeric gel-like film and the decomposition of the electrolyte solution may contribute the additional capacity. The discharge capacity of Na 3 V 2 (PO 4 ) 3 was 119.6 mAh g À1 , slightly larger than theoretical capacity (117.6 mAh g À1 ) [46]. In addition, the LiFePO 4 wrapped with the electrochemically exfoliated graphene delivered a capacity of 208 mAh g À1 m, which is beyond the theoretical capacity of 170 mAh g À1 [47].…”

Effect of process medium on the synthesis of carbon coated lithium vanadium phosphate composite using rheological phase reaction method

“…Conventionally, solidestate reaction method often results in relatively large particle size and the aggregation of materials, although the facile operation shows advantages in large-scale application [8,11]. Solegel method and hydrothermal method can realize more homogeneous mixing of raw ingredients in precursors and obtain relatively smaller particle sizes.…”