Synthesis and properties of a new (3,8)-connected pillar-layered Co(II)-based coordination polymer supported by tetranuclear secondary building units (SBUs)

Yang, Guo‐Ping; Li, Yuanpu; Wang, Dangpo; Guo, Yanjun; Hao, Wenle; Wang, Yao‐Yu; Shi, Qi‐Zhen

doi:10.1016/j.inoche.2014.02.015

Cited by 6 publications

(2 citation statements)

References 28 publications

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“…Meanwhile, the full deprotonated L 3– ligand displays (η 1 :η 1 )-(η 1 :η 1 )-(η 1 :η 1 )-μ 6 coordination mode to link six adjacent Cu ions with three bidentate bridging carboxylate groups. The similar coordination mode was observed in its one cobalt compound …”

Section: Resultssupporting

confidence: 73%

“…As we know, polycarboxylates are widely employed to construct MOFs with desired structures and functional properties. − Several well-known MOFs were prepared by rigid polycarboxylates such as terephthalate (MOF-5) and 1,3,5-benzenetricarboxylate (HKUST-1, MIL-100). − While, as an asymmetric semirigid V-shaped tricarboxylate ligand, − 4-(2-carboxyphenoxy)-isophthalic acid (H 3 L) has been not fully capitalized to build MOFs, , it is noted that one of its MOFs, [Zn 3 L 2 (4,4′-bpy) 2 ·H 2 O] (4,4′-bpy = 4,4′-bipyridine), exhibits a unique luminescent response to methanol . With this background in mind, we utilized H 3 L as a ligand successfully and prepared a three-dimensional (3-D) porous Cu(II) MOF [Cu 3 L 2 (H 2 O) 2.75 ]·0.75H 2 O·1.75DMA ( 1 ), with a sqc topology, which exhibits good humidity sensing properties coated on quartz crystal microbalance (QCM).…”

Section: Introductionmentioning

confidence: 99%

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Antiferromagnetic Copper(II) Metal–Organic Framework Based Quartz Crystal Microbalance Sensor for Humidity

Zhou

Wang

et al. 2017

Crystal Growth & Design

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A novel copper metal–organic framework (MOF) [Cu3L2(H2O)2.75]·0.75H2O·1.75DMA (H3L = 4-(2-carboxyphenoxy)-isophthalic acid, DMA = dimethylacetamide) has been synthesized and structurally characterized by elemental analyses, IR spectroscopy, and single-crystal X-ray diffraction. Compound 1 shows a three-dimensional architecture with a sqc topology net where the [Cu2(COO)4] unit was viewed as a node. Magnetic studies indicate that strong antiferromagnetic coupling with J = −159.0(9) cm–1 dominates in the compound. As a sensor, the compound based on quartz crystal microbalance (QCM) exhibits good linearity humidity sensing properties after being exposed to various relative humidity environments at room temperature. The resulting sensitivity is about 28.7 Hz/%RH with a good linearity coefficient of 0.993.

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Section: Resultssupporting

confidence: 73%

Section: Introductionmentioning

confidence: 99%

Antiferromagnetic Copper(II) Metal–Organic Framework Based Quartz Crystal Microbalance Sensor for Humidity

Zhou

Wang

et al. 2017

Crystal Growth & Design

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Synthesis, Structures, and Photoluminescent Properties of Three Coordination Polymers based on an Asymmetric Semi‐rigid V‐shaped Tricarboxylate Ligand

Shi¹,

Sun²,

Zhao³

et al. 2014

Zeitschrift anorg allge chemie

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Three coordination polymers, [Zn(HL)(phen)(H2O)]n (1), [Zn1.5(L)(4, 4′‐bpy)1.5]n·4nH2O (2), and [Zn2(HL)2(bib)2]n·2nH2O (3), were assembled from the asymmetric semi‐rigid V‐shaped tricarboxylate ligand 4‐(2‐carboxy‐phenoxy)‐isophthalic acid (H3L) with 1, 10‐phenanthroline (phen), 4, 4′‐bipyridine(4, 4′‐bpy) and 1, 4‐bis (imidazol‐1‐yl) benzene (bib) as auxiliary ligands. Complex 1 features a one‐dimensional (1D) double‐looped chain, which is further extended into a 2D supramolecular layer via two kinds of hydrogen‐bonding interactions. Complex 2 exhibits a complicated 3D framework, which can be rationalized as a (3, 4,4)‐connected trinodal net with a unique (4·8·10) (4·8·10·123) (82·122·14·16) topology. Complex 3 has a two‐dimensional (2D) (4, 4) layer formed by the {Zn2} dinuclear SUBs and the bib ligands. The structural and topological differences of the three complexes indicate that the N‐containing auxiliary ligands play important roles in the formation of the final framework structures. In addition, complexes 1–3 were characterized by elemental analysis, IR spectroscopy, and X‐ray powder diffraction. The thermal behaviors and luminescent properties of complexes 1–3 were also investigated in detail.

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Syntheses, structural diversity and properties of a series of coordination polymers based on 4-substituted bis(triazole) and multicarboxylate ligands

Zhu

Qian

et al. 2018

Polyhedron

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Synthesis and properties of a new (3,8)-connected pillar-layered Co(II)-based coordination polymer supported by tetranuclear secondary building units (SBUs)

Cited by 6 publications

References 28 publications

Antiferromagnetic Copper(II) Metal–Organic Framework Based Quartz Crystal Microbalance Sensor for Humidity

Antiferromagnetic Copper(II) Metal–Organic Framework Based Quartz Crystal Microbalance Sensor for Humidity

Synthesis, Structures, and Photoluminescent Properties of Three Coordination Polymers based on an Asymmetric Semi‐rigid V‐shaped Tricarboxylate Ligand

Syntheses, structural diversity and properties of a series of coordination polymers based on 4-substituted bis(triazole) and multicarboxylate ligands

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