Synthesis and properties of palladium(I) carbonyl chlorides

Fedoseev, I. V.; Gordeev, A. S.

doi:10.1134/s0036023607010020

Cited by 3 publications

(1 citation statement)

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“…Recently, the assistance of water in the formation of [PdCl(CO)] n from PdCl 2 under CO has been reported by another group. 10 The reduction of cis-PtCl 2 (CO) 2 in the presence of an excess of water has been reported by Chatt and co-workers, 11 the reaction being carried out under carbon monoxide in ethanol as medium.…”

Section: Reaction Of the Molecular Precursors With Watermentioning

confidence: 86%

Loading silica with metals (palladium or platinum) under mild conditions by using well-defined molecular precursors

et al. 2009

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The loading of pre-treated amorphous silica with platinum or palladium was carried out by using the molecular precursors Pt2(micro-Cl)2Cl2(CO)2, or Pd2(micro-Cl)2Cl2(CO)2, respectively, which contain the required amount of coordinated CO to carry out the formation of the metal particles upon contact with moisture. The reactivity of the well-soluble mononuclear platinum complex cis-PtCl2(CO)2 with stoichiometric amounts of water was investigated either under N2 or CO. The metal nanoparticles produced on the silica matrix have been characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and transmission electron microscopy (TEM). The catalytic performance of the silica-supported metals thus produced was evaluated in the hydrogenation of cyclohexene.

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Section: Reaction Of the Molecular Precursors With Watermentioning

confidence: 86%