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Secondary processing of waste from metallurgical and other industries becomes an urgent issue in the face of increasing anthropogenic pressure and a shortage of sources of materials. The paper shows the results of chemical and technological studies of processes, executing in the Cu(II)-Cu(I)-Cl-CO-H 2 О system. The processing technology of copper-bearing intermediate products multicomponent leaching solutions, permitting high purity copper production at the least economic cost, is proposed.

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A novel process for the recovery of platinum group metals (pgms) from ternary alloys using a hydrocarbonyl process is proposed. The hydrocarbonyl process involves treatment of a chloride solution of the pgms with carbon monoxide at ambient pressure. The results demonstrate that the process can provide high purity pgms from a ternary platinum-rhodium-palladium alloy such as that obtained from palladium-nickel catchment alloys used with platinum-rhodium gauzes during high temperature ammonia oxidation.