Synthesis and spectroscopic characterization of eleven mixed-ligand diorganotellurium(IV) compounds containing dithiocarbamate and dithiophosphate ligands

Cotero-Villegas, Ave María; Garcia, Patrícia Azevedo; Höpfl, Herbert; Pérez-Redondo, María del Carmen; Martínez-Salas, Patricia; López-Cardoso, Marcela; Olivares, Raymundo Cea

doi:10.1016/j.jorganchem.2010.11.006

Cited by 8 publications

(3 citation statements)

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“…For related structures, see: Chekhlov et al (1991); Chekhlov (2000). For applications of O,O 0 -diethyl dithiophosphate in coordination chemistry, see: Cotero-Villegas et al (2011). For the determination of various ions in analytical chemistry using O,O 0 -diethyl dithiophosphates, see: Carletto et al (2009); Maltez et al (2008); Pozebon et al (1998); Wu et al (2006).…”

Section: Related Literaturementioning

confidence: 99%

AmmoniumO,O′-diethyl dithiophosphate

Okuniewski

Becker

2011

Acta Cryst E

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In the title compound, NH4 +·(C2H5O)2PS2 −, the ammonium cation is connected by four charge-assisted N—H⋯S hydrogen bonds to four tetrahedral O,O′-diethyl dithiophosphate anions, forming layers parallel to (100). The polar and non-polar constituents of the layers are stacked alternately along [100]. Interlacing of the external ethyl groups through van der Waals interactions combines these layers into a three-dimensional structure.

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Section: Related Literaturementioning

confidence: 99%

AmmoniumO,O′-diethyl dithiophosphate

Okuniewski

Becker

2011

Acta Cryst E

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“…The structures of some of these compounds were unambiguously established by single crystal X-ray diffraction studies. The synthesis and characterization of mixed-ligand diorganotellurium (IV) compounds containing dithiocarbamates and dithiophosphate ligands are also reported [36].…”

Section: Scheme-imentioning

confidence: 99%

Organotellurium Compounds: From Molecular to Supramolecular Chemistry

Bajpai¹,

Shamsi²

2018

Asian J. Chem.

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“…167 R 2 Te(dithiocarbamate) (dithiophosphate) compounds display C-trigonal-bipyramidal coordination geometries, intramolecular Te-S SBIs capped two faces. 168 Investigations of 2-(R 2 NCH 2 )C 6 H 4 ]SeX (R = alkyl, X = Cl, Br, I) suggest that a Raman band between 250 and 150 cm À1 is characteristic of the molecules which feature a N-Se SBI. 169 Such interactions appear to induce luminescence in substitutes azobenzenes but the efficiency of the photophysical process does not correlate with the strength of the interaction.…”

Section: Organo-selenium Chemistrymentioning

confidence: 99%

Oxygen, sulfur, selenium, tellurium and polonium

Lee

Vargas‐Baca

2012

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem.

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This Chapter reviews the 2011 literature regarding the Group 16 elements, with an emphasis on new structures, synthesis, reactivity, new chalcogenide materials and their properties. HighlightsHighlights include the oxygen isotopic distribution of the Sun, dithiolene ligands, the mechanism of phase transition of Sb 2 Te 3 -GeTe, the phase changes of elemental Po, hydrogen evolution photo-catalysed by (Z-MeC 5 H 4 )Mo 3 S 4 clusters on silicon. Elemental chalcogens and chalcogenidesElements Isotopic measurements of captured solar wind revealed that, compared to Earth, the Sun is highly enriched in 16 O. 1 The F À affinity of O 2 was estimated (CCSD(T)/CBS) to be 1.6 kcal mol À1 . 2 Elemental sulfur was used as a new medium to synthesise gold nanoparticles, which enhances the mechanical properties of the dispersion. 3 A combination of grazing incidence inelastic X-ray scattering and calculations (ab initio/semiempirical) provided a structural model of the top 5 nm of amorphous selenium in which a high concentration of coordination defects at the surface explains the differences in vibrational dynamics with the bulk. 4 DFT calculations predict a transition of Po from the cubic structure to a mixture of two trigonal phases near 2 GPa. 5 Large-scale atomic calculations for the electronic factor F and specific mass shift M SMS successfully reproduced in-source resonant ionisation spectroscopic measurements for the polonium isotopes from 192 Po to 218 Po. 6 OxidesOxygen deficiency in RbO 2 enables order-disorder transitions based on the orientation of the anions; in RbO 1.72 , the changes result in short-range ferromagnetic ordering below 50 K. 7 Computational studies (B3LYP/6-311++G and MP2/6-311++G

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Synthesis and spectroscopic characterization of eleven mixed-ligand diorganotellurium(IV) compounds containing dithiocarbamate and dithiophosphate ligands

Cited by 8 publications

References 20 publications

AmmoniumO,O′-diethyl dithiophosphate

AmmoniumO,O′-diethyl dithiophosphate

Organotellurium Compounds: From Molecular to Supramolecular Chemistry

Oxygen, sulfur, selenium, tellurium and polonium

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