Synthesis and structure–activity relationship of benzylamine supported platinum(iv) complexes

Synthesis, Characterization, Anticancer, DNA Binding and Antioxidant Studies of Benzylamine Supported Pd (II) Complex

“…The overall patterns of spectra for complexes solution were found similar with the different mediums to ensure their sustainability in liquid state. The UV/Vis absorption from 265 to 270 nm and 1H NMR coupling constant between 5 and 9 MHz, have confirmed their trans geometry [18,23,24]. benzenesulfonate (SRB) assay [25], and compared with adriamycin (ADR) and cisplatin [26].…”

A Novel Approach of Partial Derivatives to Estimate the Normal Boiling Temperature via Viscosity Arrhenius Behaviour in N,N-Dimethylformamide + Ethanol Fluid Systems

“…Consequently, as mentioned in the literature that the cohesive forces characterizes the surface tension so for well clarification of the surface tension along with absolute viscosity measurements are of thermodynamic significance interfaced by the friccohesity [28][29][30][31][32][33][34]. Furthermore, correlation between the Arrhenius parameters and the temperature, by means of the temperature of vapourization is greatly affected by the friccohesity, the molar enthalpy of vapourization and the surface tension [28][29][30][31][32][33][34].…”

“…Theory of solutions is still far from sufficient to well treat non-idealities for liquid solution, in terms of properties of the constituent molecules [28][29][30][31][32][33][34]. The knowledge of the principal factors engaged in the non-ideality of fluid mixtures is important for a better understanding of excess viscosities and volumes and its derived functions.…”

“…Thus it acts as a protophilic aprotic solvent of large dipole moment (µ = 3.80 D) of molecules with a fairly high dielectric constant (ε = 36.71) at 298.15 K [1][2][3][4][5]. An ethanol molecule can interact with a N,N-dimethyl-formamide molecule in accordance with the better hydrogen bonding acceptor ability of its oxygen atom, resulting in packing and structural effects in the light of the critical interface of cohesive and frictional forces represented by friccohesity [28][29][30][31][32][33][34].…”

“…In view of the data given from the literature and augmented by some interpolation operations for derivations needed, it is extended to examine the viscosity Arrhenius-type behaviour along with a new coefficients nominated as Arrhenius temperature (TA), in ethanol + N,N-dimethylformamide binary fluid mixtures from 303.1 to 323.15 K [28][29][30][31][32][33][34].…”