Synthesis and structures of polymeric silver and mercury complexes with amido-functionalized N-heterocyclic carbenes

Ionic‐Liquid‐Functionalized UiO‐66 Framework: An Experimental and Theoretical Study on the Cycloaddition of CO2 and Epoxides

“…[57,58] ILA@U6N and ILB@U6N bifunctional catalysts were synthesized by couplingr eactions of UiO-66-NH 2 and the ILs, and the structuraland physical properties were studied in detail. [57,58] ILA@U6N and ILB@U6N bifunctional catalysts were synthesized by couplingr eactions of UiO-66-NH 2 and the ILs, and the structuraland physical properties were studied in detail.…”

“…UiO-66-NH 2 and imidazolium-basedI Ls were prepared according to literature procedures. [57,58] ILA@U6N and ILB@U6N bifunctional catalysts were synthesized by couplingr eactions of UiO-66-NH 2 and the ILs, and the structuraland physical properties were studied in detail. Freshly dried UiO-66-NH 2 and 1methylacetamido-3-methylimidazolium bromide (for ILA@U6N) or 1-methylacetamido-3-methylbenzimidazolium bromide (for ILB@U6N) were suspended in methanola nd the mixture was heated to reflux for 48 ha t6 08Cw ith continuous stirring.…”

Di‐ and Trinuclear Gold Complexes of Diphenylphosphinoethyl‐Functionalised Imidazolium Salts and their N‐Heterocyclic Carbenes: Synthesis and Photophysical Properties

“…Interestingly, as observed for 5, a sophisticated [Ag 2 Br 5 ] 3À ion was discovered in the structure showing that the formation of polynuclear silver(I) halide anions is evidently preferred. Although some bromoargentate anions like [Ag 2 Br 6 ] 4À in general [89,90] or [Ag 4 X 8 ] 4À , [91] isolated from the silver oxide route, have been reported in carbene chemistry, the occurrence of this [Ag 2 Br 5 ] 3À ion is to the best of our knowledge unknown in carbene synthesis with silver oxide. The ESI-mass spectrum of a bulk sample of 6 shows the same signal for the triply charged [(L2) 2 Au 3 ] 3 + ion as well as signals corresponding to the monocation [{(L2) 2 Au 3 }{Br} 2 ] + .…”

Coinage Metal Complexes of Bis‐Alkynyl‐Functionalized N‐Heterocyclic Carbenes: Reactivity, Photophysical Properties, and Quantum Chemical Investigations

“…Complex 7 crystallizes in the triclinic space group P1 with half of am olecule and one molecule of CH 2 Cl 2 in the asymmetricu nit ( Figure 3). According to this result,t he carbene trans- metalation reactionf ully took place, but instead of the formation and precipitation of bulk silver halides, they were incorporatedi nt he final complex.W hereast he formation of the polynuclear [Ag n X m ] zÀ anions wasr eported earlier, [61][62][63][64][65][66][67] the metal atoms are linked togetherb ym etallophilic interactions in this case. According to this result,t he carbene trans- metalation reactionf ully took place, but instead of the formation and precipitation of bulk silver halides, they were incorporatedi nt he final complex.W hereast he formation of the polynuclear [Ag n X m ] zÀ anions wasr eported earlier, [61][62][63][64][65][66][67] the metal atoms are linked togetherb ym etallophilic interactions in this case.…”

“…Chem.E ur.J. 2017, 23,1591 -1603 www.chemeurj.org metalation reactionf ully took place, but instead of the formation and precipitation of bulk silver halides, they were incorporatedi nt he final complex.W hereast he formation of the polynuclear [Ag n X m ] zÀ anions wasr eported earlier, [61][62][63][64][65][66][67] the metal atoms are linked togetherb ym etallophilic interactions in this case. The Au1ÀAg1 distance of 2.9279(8) is in as imilar range to that of [(NHC Alkyl ) 4 (Au 2 Ag 2 Br 4 )] (Alkyl = C 14 H 29 , d Au···Ag % 3.0 ).…”