Synthesis and thermal investigations of ruthenium(II) phenanthroline complexes of [Ru(phen)3]X2 type, where XCl−, Br−, I−, SCN−, VO3−, ReO4−

Bujewski, A.; Walewski, M.; Grzedzicki, K.; Dobrowolski, J.

doi:10.1016/0040-6031(90)80113-d

Cited by 3 publications

(1 citation statement)

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“…Both reagents are known to produce strong CL using a portfolio of oxidants and in the presence of many analytes. However, Ru(phen) 3 2+ is utilized to a much lesser extent than Ru(bpy) 3 2+ as CL reagent in chemical analysis, despite the fact that in many applications it was found to be of an equivalent or higher CL efficiency compared to Ru(bpy) 3 2+ (14,(17)(18)(19)(20). Methods for the assay of barbituric acid in synthetic samples, enoxacin and isoniazid were developed using Ru(phen) 3 2+ and very low detection limits were obtained (18,19,21).…”

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confidence: 99%

Chemiluminescence determination of chlorpheniramine using tris(1,10‐phenanthroline)–ruthenium(II) peroxydisulphate system and sequential injection analysis

et al. 2008

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] and a peristaltic pump to propel the sample. The experimental conditions affecting the chemiluminescence reaction were systematically optimized, using the univariate approach. Under the optimum conditions linear calibration curves of 0.1-10 mg/ml were obtained. The detection limit was 0.04 mg/ml and the relative standard deviation (RSD) was always < 5%. The procedure was applied to the analysis of CPA in pharmaceutical products and was found to be free from interferences from concomitants usually present in these preparations.

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