Synthesis, Characterization and Adsorption Capability of MOF-5

Iswarya, N.; Kumar, Mohit; Rajan, K.; Rayappan, John Bosco Balaguru

doi:10.3923/ajsr.2012.247.254

Cited by 22 publications

(11 citation statements)

References 19 publications

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“…3a and 3d). [17] The cubical structure has occurred more, and some cluster-like arrangement also present which shows the adsorption property of MOF-5, its shows in the (Fig. 3b and 3c).…”

Section: Surface Morphology Of Mof-5mentioning

confidence: 86%

“…The FTIR spectra of MOF-5 shown in framework structure. [17] XRD analysis of MOF-5 X-ray diffraction analysis of MOF-5 shown in Fig. 2.…”

Section: Ftir Characterization Of Mof-5mentioning

confidence: 99%

“…The peaks at 6.8°, 9.7°, 14° and 15.8° in 2θ which indicates the formation of a crystalline structure. [17] The inconsistency peaks appear due to the framework interpenetration and pore occupation. The intensities of the two peaks were overturned that can be attributed to some alterations of atomic orientations in the crystal planes by absorbed species (solvent and water molecules), unreacted zinc centers and framework interpenetration.…”

Section: Ftir Characterization Of Mof-5mentioning

confidence: 99%

“…The peak appearance indicate the Zn metal ion attach with carboxylate ligand and it proves the formation of MOF-5 by the interaction of metal ion and organic cluster. [17]…”

Section: Energy Dispersive X-ray Spectroscopy Of Mof-5mentioning

confidence: 99%

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Removal of hazardous material from wastewater by using metal organic framework (MOF) embeddedpolymeric membranes

Gnanasekaran

Balaguru

Arthanareeswaran

et al. 2018

Separation Science and Technology

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Heavy metals in wastewater can cause acute and chronic toxicity which leads to learning disabilities, cancer, and even death. In present work, Zn based MOF (MOF-5) was prepared, and it is characterized by FT-IR, XRD, and SEM Analysis. MOF-5 incorporated polymeric membranes (PES, CA and PVDF) prepared by phase inversion method. The morphology, hydrophilicity, porosity, permeation performance, antifouling properties and the rejection of Cu (II) and Co (II) metal ions of the membranes were significantly improved with the addition MOF-5. Higher rejection efficiency for Co (II) in PES/MOF-5 and CA/MOF-5 was found to be 74.40 % and 77 % respectively.

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“…3a and 3d). [17] The cubical structure has occurred more, and some cluster-like arrangement also present which shows the adsorption property of MOF-5, its shows in the (Fig. 3b and 3c).…”

Section: Surface Morphology Of Mof-5mentioning

confidence: 86%

“…The FTIR spectra of MOF-5 shown in framework structure. [17] XRD analysis of MOF-5 X-ray diffraction analysis of MOF-5 shown in Fig. 2.…”

Section: Ftir Characterization Of Mof-5mentioning

confidence: 99%

Section: Ftir Characterization Of Mof-5mentioning

confidence: 99%

“…The peak appearance indicate the Zn metal ion attach with carboxylate ligand and it proves the formation of MOF-5 by the interaction of metal ion and organic cluster. [17]…”

Section: Energy Dispersive X-ray Spectroscopy Of Mof-5mentioning

confidence: 99%

See 2 more Smart Citations

Removal of hazardous material from wastewater by using metal organic framework (MOF) embeddedpolymeric membranes

Gnanasekaran

Balaguru

Arthanareeswaran

et al. 2018

Separation Science and Technology

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show abstract

“…29 MOF-5 is one of the most widely used MOFs and uses a very cheap organic linker (terephthalate) along with inorganic {Zn 4 O} 6+ nodes based on abundant and benign zinc. 30,31 Herein, we will present the results obtained by this simple yet efficient strategy. First, we will confirm the inclusion of the BODIPY dye in the final material and quantify its loading rate.…”

Section: Introductionmentioning

confidence: 99%

Carboxylate BODIPY integrated in MOF-5: easy preparation and solid-state luminescence

Tran,

Leroux,

Michelin

et al. 2023

J. Mater. Chem. C

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Tailoring the Effect of NiCo‐Metal‐Organic Frameworks by Doping Manganese as a Highly Active Redox Electrode for Electrochemical Energy Storage Technologies: Supercapattery Devices

Zahid,

Abdul Karim,

Khalid

et al. 2024

Energy Tech

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Metal–organic frameworks with complex geometry have garnered significant attention in technological fields due to their diverse properties. Multimetallic metal‐organic frameworks (MOFs) have potential to demonstrate superior conductivity and efficiency compared to pristines, but, they have not been explored to research on large scale. Herein, significant effect of binary (NiCo‐) and ternary (NiCoMn‐) MOFs is explored with a novel approach using an organic ligand hexamethylene tetra‐amine (HMT). The as‐synthesized MOFs with their distinctive structures are thoroughly examined to analyze their structural, morphological, and electrochemical properties. In a standard half‐cell setup, the electrochemical behaviors of both samples are investigated, as both electrodes exhibit specific capacities of 349 and 905 C g−1, at 3 mV s−1, individually. Due to promising electrochemical responses of NiCoMnMOF, a supercapattery device is constructed as NiCoMnMOF//AC. This hybridization leads to the remarkable specific energy (78 Wh kg−1) and specific power (3500 W kg−1) with stability rate of ≈96% and Coulombic efficiency of 99% after undergoing 5000 galvanostatic charge–discharge cycles, making it highly suitable for modern applications. To gain better insight of supercapattery device, a semiempirical approach is employed, using Dunn's modulation. Thus, the synergy of NiCoMnMOF//AC in the single hybrid device exhibiting battery‐like characteristics holds tremendous potential for driving innovations in energy storage technology.

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Synthesis, Characterization and Adsorption Capability of MOF-5

Cited by 22 publications

References 19 publications

Removal of hazardous material from wastewater by using metal organic framework (MOF) embeddedpolymeric membranes

Removal of hazardous material from wastewater by using metal organic framework (MOF) embeddedpolymeric membranes

Carboxylate BODIPY integrated in MOF-5: easy preparation and solid-state luminescence

Tailoring the Effect of NiCo‐Metal‐Organic Frameworks by Doping Manganese as a Highly Active Redox Electrode for Electrochemical Energy Storage Technologies: Supercapattery Devices

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