Synthesis, characterization and adsorption performance of a novel post-crosslinked adsorbent

Zeng, Xiaowei; Yao, Hongjie; Ma, Ning; Fan, Yunge; Wang, Chunhong; Shi, Ruizhi

doi:10.1016/j.jcis.2010.10.032

Cited by 24 publications

(15 citation statements)

References 48 publications

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“…Moreover, adsorption of phenol on MSE-resin is spontaneous as indicated by the negative DG values. The positive values of DS reflect that the randomness of the solid-solution interface is increased during the sorption of phenol on MSE-resin (Zeng et al, 2011).…”

Section: Adsorption Thermodynamicsmentioning

confidence: 96%

Adsorption of Phenol from Aqueous Solutions Using a Hydrophilic Acrylic Ester Resin

YangMan

HuangYun

CaoHaijun

et al. 2015

Environmental Engineering Science

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A new hydrophilic acrylic ester resin (MSE-resin) was synthesized by suspension polymerization from methyl methacrylate (MMA), sodium p-styrene sulfonate (SSS), and ethylene glycol dimethacrylate (EGDMA). Batch adsorption studies indicated that the optimum adsorption was achieved when pH was 5, contact time 180 min, adsorbent dose 0.2 g, initial concentration 2,000 mg/L, and temperature 313 K. Experimental data showed a good fit with the pseudosecond-order kinetic model. Intraparticle diffusion analysis indicated that the intraparticle diffusion was involved in the adsorption process, but it was not the only rate-limiting step. Adsorption isotherms of phenol were linearly correlated and found to be well represented by the Freundlich model. Thermodynamic parameters such as changes in the enthalpy (DH), free energy (DG), and entropy (DS) indicated that the process of adsorption phenol on MSE-resin was endothermic and spontaneous.

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Section: Adsorption Thermodynamicsmentioning

confidence: 96%

Adsorption of Phenol from Aqueous Solutions Using a Hydrophilic Acrylic Ester Resin

YangMan

HuangYun

CaoHaijun

et al. 2015

Environmental Engineering Science

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“…3b. This porous surface morphology is caused by the incorporation of cross-linking agent (EGDMA) which makes the VE resin constructed in three dimension directions and then presented the stereo network structure [27,29]. The EDS analysis based on the image of VE resin is also shown in Fig.…”

Section: Morphological Analysismentioning

confidence: 97%

“…The concentration of the residual phenol solution was measured and the equilibrium adsorption capacity was calculated with Eq. (2) [27]:…”

Section: Batch Adsorption Experimentsmentioning

confidence: 99%

A novel polymeric adsorbent by a self-doped manner: synthesis, characterization, and adsorption performance to phenol from aqueous solution

et al. 2016

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The organic-inorganic self-doped poly (vinyltrimethoxy silane-ethylene glycol dimethacrylate) (VE resin) was synthesized by solution polymerization, hydrolysis and dehydration condensation. In this method, ethylene glycol dimethacrylate (EGDMA) was used as cross-linked reagent to form a three-dimensional network structure. Then, the system was prepared by radical polymerization in the presence of the hydrolysis of -OCH 3 and the dehydration condensation of Si-OH. The maximum adsorption capacity 75.68 mg g -1 was achieved when pH was 6, the contact time 60 min, the adsorbent dose 0.1 g, the initial concentration 3000 mg L -1 and the temperature 293 K. The adsorption kinetics followed the pseudo-second-order kinetic model, and the intra-particle diffusion was but not the only rate-limiting step. Adsorption isotherms of phenol were linearly correlated and found to be well represented by the Freundlich model. Thermodynamic parameters such as changes in the enthalpy (DH), free energy (DG) and entropy (DS) indicated that the adsorption process of phenol on VE resin were physical and exothermic. After four regeneration recycles, the adsorption capacity of VE resin remained at 95.04 % of the initial value, which illustrated that it possessed good regeneration capacity.

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“…The starting copolymer beads were prepared as described previously with slight modification [26,27]. Briefly, the organic phase composed of the monomers DVB (40 g) and N-VP (10 g), toluene (60 ml) and heptane (30 mL) as porogen and AIBN (0.5 g) as initiator, was added to the aqueous phase (500 mL), containing PVA (1 wt% in relation to water) and NaCl (10 wt% in relation to water).…”

Section: Preparation Of the Precursor Copolymer Pnvp-dvbmentioning

confidence: 99%

Enhanced adsorption of puerarin onto a novel hydrophilic and polar modified post-crosslinked resin from aqueous solution

Zeng

Chen

Zheng

et al. 2012

Journal of Colloid and Interface Science

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Synthesis, characterization and adsorption performance of a novel post-crosslinked adsorbent

Cited by 24 publications

References 48 publications

Adsorption of Phenol from Aqueous Solutions Using a Hydrophilic Acrylic Ester Resin

Adsorption of Phenol from Aqueous Solutions Using a Hydrophilic Acrylic Ester Resin

A novel polymeric adsorbent by a self-doped manner: synthesis, characterization, and adsorption performance to phenol from aqueous solution

Enhanced adsorption of puerarin onto a novel hydrophilic and polar modified post-crosslinked resin from aqueous solution

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