Synthesis, characterization, and biological properties of Ni(II), Co(II), and Cu(II) complexes of Schiff bases derived from 4-aminobenzylamine

Demetgül, Cahıt; Karakaplan, Mürüvvet; Serın, Selahattın; Dığrak, Metin

doi:10.1080/00958970903082192

Cited by 37 publications

(10 citation statements)

References 25 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In addition, the weak vibration bands observed at 645-500 cm −1 can be attributed to metal-N and metal-O bonds. Moreover, the bands of azomethine groups of polymers are slightly shifted to lower frequencies in the complexes [25]. This change in frequencies shows that the azomethine nitrogen coordinates to the metal ion.…”

Section: Structures Of the Polymers And Polymer-metal Complexesmentioning

confidence: 82%

“…As being different from monomers, the polymers' absorption region in 450-600 nm can be caused by their long polymer structure systems [24]. In the spectra of the complexes the bands of the azomethine n-π * transition are shifted to lower frequencies, indicating that the azomethine nitrogen atoms are involved in coordination to the metal ions [25]. In addition, the weak bands observed in the 500-700 nm region can be attributed to d-d transitions of the metal ions.…”

Section: Structures Of the Polymers And Polymer-metal Complexesmentioning

confidence: 99%

See 1 more Smart Citation

Schiff Base Polymers Obtained by Oxidative Polycondensation and Their Co(II), Mn(II) and Ru(III) Complexes: Synthesis, Characterization and Catalytic Activity in Epoxidation of Styrene

Demetgül

Delikanlı

Sarıbıyık

et al. 2012

Designed Monomers and Polymers

Self Cite

View full text Add to dashboard Cite

In this paper, Schiff base monomers having double azomethine groups, N,N -bis(4-hydroxybenzylidene)1, 4-phenylenediamine (M 1 ) and N,N -bis(4-hydroxysalicylidene)1,4-phenylenediamine (M 2 ), were prepared by a common condensation reaction between 4-hydroxybenzaldehyde and 4-hydroxysalicylaldehyde with 1,4-phenylenediamine, respectively. The new Schiff base polymers, poly(N,N -bis(4-hydroxybenzylidene)1,4-phenylenediamine) (P 1 ) and poly(N,N -bis(4-hydroxysalicylidene)1,4-phenylenediamine) (P 2 ) were synthesized from the oxidative polycondensation of monomers with NaOCl in an aqueous alkaline medium. The characterization of synthesized monomers and polymers was carried out by FT-IR, UV-Vis, 1 H-NM, 13 C-NMR and elemental analysis. The new polymer-metal complexes were prepared by using polymers and Co(II), Mn(II) and Ru(III) metal salts. Thermal properties of the compounds were studied by TG-DTA techniques. In addition, the catalytic properties of the polymers and their metal complexes were investigated in epoxidation reactions of styrene. The results of the catalysis studies were monitored by GC-MS.

show abstract

Section: Structures Of the Polymers And Polymer-metal Complexesmentioning

confidence: 82%

Section: Structures Of the Polymers And Polymer-metal Complexesmentioning

confidence: 99%

Schiff Base Polymers Obtained by Oxidative Polycondensation and Their Co(II), Mn(II) and Ru(III) Complexes: Synthesis, Characterization and Catalytic Activity in Epoxidation of Styrene

Demetgül

Delikanlı

Sarıbıyık

et al. 2012

Designed Monomers and Polymers

Self Cite

View full text Add to dashboard Cite

show abstract

“…In the IR spectra of both complexes, the strong bands observed at 1629 cm ¡1 for (1) and 1623 cm ¡1 for (2) are assigned to the azomethine group vibration. [15] The typical bands at 3219 cm ¡1 in (1) and 3227 cm ¡1 in (2) are attributed to the stretching vibrations of the amino groups. The characteristic intense band indicative (1) is located at 2046 cm ¡1 .…”

Section: Infrared Spectramentioning

confidence: 98%

Schiff Base Copper(II) and Zinc(II) Complexes: Synthesis, Structures, and Antimicrobial Activities

Zhao

Xue

Zhang

2014

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-

View full text Add to dashboard Cite

A new halo-substituted Schiff base ligand 2-bromo-6-[(2-ethylaminoethylimino)methyl]phenol (HL) and its copper(II) and zinc(II) complexes [Cu 2 L 2 (m 1,1 -NCS) 2 ] (1) and [ZnCl 2 (HL)] (2) (HL is the zwitterionic form of the Schiff base ligand) have been prepared and characterized by elemental analyses, IR, and single-crystal X-ray crystallographic determination. The crystal of (1) is monoclinic: space group P2 1 /c, a D 10.909 (1), b D 13.976(1), c D 10.161(1) A , b D 111.471(2) , V D 1441.7(2) A 3 , Z D 2. The crystal of (2) is monoclinic: space group P2 1 /n, a D 7.2682(4), b D 20.195(1), c D 10.8447(6) A , b D 106.420(2) , V D 1526.9(2) A 3, Z D 4. The Cu atoms in the copper complex are in square pyramidal coordination. The Zn atom in the zinc complex is in tetrahedral coordination. The effect of the complexes on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans were studied.

show abstract

“…The standardized disk-diffusion method 11,12 was followed to determine the activity of the synthesized compounds against the sensitive organisms Gram-positive (staphylococcus auerus) and Gram-negative bacteria (pseudomonas fluorescens) and (Aspergillus fumigatus) Streptomycin was used as a standard reference in the case of bacteria while Fluconazole was used as a standard antifungal reference.…”

Section: Antimicrobial Activitymentioning

confidence: 99%

Synthesis, Characterization, Electrochemical and Antimicrobial Activity of Macrocyclic Binuclear Cu(II), Ni(II) and VO(II) Schiff Base Complexe

D¹,

Vedanayaki²,

Rajavel³

2013

Chem Sci Trans

View full text Add to dashboard Cite

). Structural characterization of the complexes were achieved by several physicochemical methods, namely elemental analysis, electronic spectra, infrared, EPR, cyclic voltammetry, molar conductivity and magnetic susceptibility measurements. A square planar binuclear structure was proposed for the perchlorate anions in Cu(II) and Ni(II) complexes. Whereas the square pyramidal environment around the VO(II) center. The Schiff base complexes were investigated for antibacterial and antifungal properties of gram-positive bacteria (staphylococcus auerus), gramnegative bacteria (pseudomonas fluorescens) and fungi (Aspergillus fumigatus) were used in this study to assess their antimicrobial properties. The results showed that this skeletal framework exhibit marked potency as antimicrobial agents.

show abstract

Synthesis, characterization, and biological properties of Ni(II), Co(II), and Cu(II) complexes of Schiff bases derived from 4-aminobenzylamine

Cited by 37 publications

References 25 publications

Schiff Base Polymers Obtained by Oxidative Polycondensation and Their Co(II), Mn(II) and Ru(III) Complexes: Synthesis, Characterization and Catalytic Activity in Epoxidation of Styrene

Schiff Base Polymers Obtained by Oxidative Polycondensation and Their Co(II), Mn(II) and Ru(III) Complexes: Synthesis, Characterization and Catalytic Activity in Epoxidation of Styrene

Schiff Base Copper(II) and Zinc(II) Complexes: Synthesis, Structures, and Antimicrobial Activities

Synthesis, Characterization, Electrochemical and Antimicrobial Activity of Macrocyclic Binuclear Cu(II), Ni(II) and VO(II) Schiff Base Complexe

Contact Info

Product

Resources

About