“…These include drugs, cosmetics, dyes, and inks, and for the protection of fillers, catalysts, and pigments due to their advantageous properties like low density, large specific area, mechanical and thermal stability, and surface permeability [3][4][5][6]. Therefore, a variety of chemical and physicochemical approaches have been employed to prepare hollow spheres, such as: self-assembly routes [7], sonochemical process [8], hydrothermal method [9], emulsion/interfacial polymerization strategies [10], and template-assisting techniques including "hard templates," such as silica spheres [11], polystyrene microspheres [12], and "soft templates," such as vesicles [13], and emulsion droplets [14].…”