Synthesis, Characterization, and Reversible Multielectron Redox Properties of a Biradical Yttrium Complex Containing Bis(2‐isopropylaminophenyl)amide

Duan, Lili; Jia, Yibo; Li, Xiaogen; Li, Yue‐Ming; Hu, Hongfan; Li, Jianfeng; Cui, Chunming

doi:10.1002/ejic.201601457

Cited by 8 publications

(1 citation statement)

References 68 publications

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“…The ligand contains a bis(aminophenyl)aminate ([NNN] 3– ) framework whose redox activity has been previously studied. 23 – 28 Our ligand differs from those of the previous studies through the functionalization of the redox-active framework with two sulfonamido units ( Fig. 1 ), which we and others have shown can produce metal complexes with diverse structures and functions.…”

Section: Introductionmentioning

confidence: 74%

Mononuclear complexes of a tridentate redox-active ligand with sulfonamido groups: structure, properties, and reactivity

et al. 2018

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Section: Introductionmentioning

confidence: 74%

Mononuclear complexes of a tridentate redox-active ligand with sulfonamido groups: structure, properties, and reactivity

et al. 2018

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Coordination Chemistry with Lanthanides and Redox‐Active Ligands

Cemortan,

Nocton

2024

Redox‐Active Ligands

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Lanthanoid Complexes as Molecular Materials: The Redox Approach

Hay

Boskovic

2021

Chemistry A European J

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The development of molecular materials with novel functionality offers promise for technological innovation. Switchable molecules that incorporate redox‐active components are enticing candidate compounds due to their potential for electronic manipulation. Lanthanoid metals are most prevalent in their trivalent state and usually redox‐activity in lanthanoid complexes is restricted to the ligand. The unique electronic and physical properties of lanthanoid ions have been exploited for various applications, including in magnetic and luminescent materials as well as in catalysis. Lanthanoid complexes are also promising for applications reliant on switchability, where the physical properties can be modulated by varying the oxidation state of a coordinated ligand. Lanthanoid‐based redox activity is also possible, encompassing both divalent and tetravalent metal oxidation states. Thus, utilization of redox‐active lanthanoid metals offers an attractive opportunity to further expand the capabilities of molecular materials. This review surveys both ligand and lanthanoid centered redox‐activity in pre‐existing molecular systems, including tuning of lanthanoid magnetic and photophysical properties by modulating the redox states of coordinated ligands. Ultimately the combination of redox‐activity at both ligands and metal centers in the same molecule can afford novel electronic structures and physical properties, including multiconfigurational electronic states and valence tautomerism. Further targeted exploration of these features is clearly warranted, both to enhance understanding of the underlying fundamental chemistry, and for the generation of a potentially important new class of molecular material.

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Synthesis, Characterization, and Reversible Multielectron Redox Properties of a Biradical Yttrium Complex Containing Bis(2‐isopropylaminophenyl)amide

Cited by 8 publications

References 68 publications

Mononuclear complexes of a tridentate redox-active ligand with sulfonamido groups: structure, properties, and reactivity

Mononuclear complexes of a tridentate redox-active ligand with sulfonamido groups: structure, properties, and reactivity

Coordination Chemistry with Lanthanides and Redox‐Active Ligands

Lanthanoid Complexes as Molecular Materials: The Redox Approach

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