Synthesis, characterization, and spectroscopic properties of binuclear copper(I) complexes with N^N-N^N, N^N^OH, N^C^N, and phosphine ligands

Gan, Xueping; Yao, Zu-Fu; Zhang, Junfeng; Li, Zheng; Fu, Wen‐Fu

doi:10.1080/00958972.2010.502965

Cited by 7 publications

(1 citation statement)

References 41 publications

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“…Mononuclar and binuclear copper(I) complexes containing diphosphine and N-heterocyclic ligands have been the focus of several investigations in the last few years because of their luminescence properties, interesting structures and novel reactivity performances [3][4][5]. During our previous work, a number of mixed-ligand coordination compounds of copper(I) salts with heterocyclic nitrogen ligands and diphosphanes were prepared and structurally characterized [6,7].…”

Section: Discussionmentioning

confidence: 99%

Crystal structure of μ-1,4-bis(diphenylphosphine)butane-2,9-dimethyl-1,10-phenanthroline-κ² N:N′-bis(cyano-κC)dicopper(I)]-water, C₅₈H₅₆Cu₂N₆O₂P₂

Zhang

Liu

et al. 2017

Zeitschrift Für Kristallographie - New Crystal Structures

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C 58 H 56 Cu 2 N 6 O 2 P 2 , monoclinic, P21/n, a = 12.0546(9) Å, b = 13.1669(10) Å, c = 16.7151(12) Å, β = 101.845(2)°, CCDC no.: 1543452 The crystal structure (water molecular removed) is shown in the figure. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters. Source of materialA mixture of CuCN (0.0179 g, 0.2 mmol), 2,9-dimethyl-1,10-phenanthroline (dmp) (0.0434 g, 0.2 mmol) and 1,4-bis(diphenylphosphino)butane (dppb) (0.0853 g, 0.2 mmol) were dissolved in a mixture of CH 3 CN and CH 2 Cl 2 (10 mL, v/v = 1:1). After being stirred for 6 hours at room temperature, the liquid was filtered. Subsequent slow evaporation of the filtrate resulted in the formation of yellow block crystals. Experimental detailsHydrogen atoms were placed on calculated positions and refined using a riding model. The highest residual electron density peak (0.67 e −3 Å) is located 2.29 Å away from the water oxygen atom; however, refinement of disorder did not lead to a significant improvement of the model.

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Section: Discussionmentioning

confidence: 99%

Crystal structure of μ-1,4-bis(diphenylphosphine)butane-2,9-dimethyl-1,10-phenanthroline-κ² N:N′-bis(cyano-κC)dicopper(I)]-water, C₅₈H₅₆Cu₂N₆O₂P₂

Zhang

Liu

et al. 2017

Zeitschrift Für Kristallographie - New Crystal Structures

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Synthetic protocols and applications of copper(I) phosphine and copper(I) phosphine/diimine complexes

Babgi

2021

Journal of Organometallic Chemistry

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Synthesis and structural characterization of five new copper (I) complexes with 1,10-phenanthroline and 1,4-bis(diphenylphosphino)butane(dppb)

Fan

Min-Liu

et al. 2015

Journal of Molecular Structure

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Synthesis, characterization, and spectroscopic properties of binuclear copper(I) complexes with N^N-N^N, N^N^OH, N^C^N, and phosphine ligands

Cited by 7 publications

References 41 publications

Crystal structure of μ-1,4-bis(diphenylphosphine)butane-2,9-dimethyl-1,10-phenanthroline-κ² N:N′-bis(cyano-κC)dicopper(I)]-water, C₅₈H₅₆Cu₂N₆O₂P₂

Crystal structure of μ-1,4-bis(diphenylphosphine)butane-2,9-dimethyl-1,10-phenanthroline-κ² N:N′-bis(cyano-κC)dicopper(I)]-water, C₅₈H₅₆Cu₂N₆O₂P₂

Synthetic protocols and applications of copper(I) phosphine and copper(I) phosphine/diimine complexes

Synthesis and structural characterization of five new copper (I) complexes with 1,10-phenanthroline and 1,4-bis(diphenylphosphino)butane(dppb)

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Synthesis, characterization, and spectroscopic properties of binuclear copper(I) complexes with N^N-N^N, N^N^OH, N^C^N, and phosphine ligands

Cited by 7 publications

References 41 publications

Crystal structure of μ-1,4-bis(diphenylphosphine)butane-2,9-dimethyl-1,10-phenanthroline-κ2 N:N′-bis(cyano-κC)dicopper(I)]-water, C58H56Cu2N6O2P2

Crystal structure of μ-1,4-bis(diphenylphosphine)butane-2,9-dimethyl-1,10-phenanthroline-κ2 N:N′-bis(cyano-κC)dicopper(I)]-water, C58H56Cu2N6O2P2

Synthetic protocols and applications of copper(I) phosphine and copper(I) phosphine/diimine complexes

Synthesis and structural characterization of five new copper (I) complexes with 1,10-phenanthroline and 1,4-bis(diphenylphosphino)butane(dppb)

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Crystal structure of μ-1,4-bis(diphenylphosphine)butane-2,9-dimethyl-1,10-phenanthroline-κ² N:N′-bis(cyano-κC)dicopper(I)]-water, C₅₈H₅₆Cu₂N₆O₂P₂

Crystal structure of μ-1,4-bis(diphenylphosphine)butane-2,9-dimethyl-1,10-phenanthroline-κ² N:N′-bis(cyano-κC)dicopper(I)]-water, C₅₈H₅₆Cu₂N₆O₂P₂