Synthetic protocols and applications of copper(I) phosphine and copper(I) phosphine/diimine complexes

Overview of the Synthesis and Catalytic Reactivity of Transition Metal Complexes Based on C═P Bond Systems

“…187−189 This also applies to complexes containing phosphorus ligands. 190,191 Similar statements can be made about the silver and gold complexes. 192−194 2.8.1.…”

“…Cu, Ag, and Au constitute an interesting group and their complexes are used in many areas. Copper complexes not only are widely used as catalysts but also are of great biological and medical importance. − This also applies to complexes containing phosphorus ligands. , Similar statements can be made about the silver and gold complexes. − …”

Antibactericidal Ir(III) and Ru(II) Complexes with Phosphine‐Alkaloid Conjugate and Their Interactions with Biomolecules: A Case of N‐Methylphenethylamine

“…Moreover, phosphines are σ‐donor and π‐acceptor ligands that stabilize mainly low oxidation states of soft metals. Furthermore, their electronic properties can be extensively modified by changing the R groups [22,24,25] . For example, auranofin (Au(I) complex) and RAPTA‐C (Ru(II) complex) are compounds composed of a phosphine fragment and are/were present in the clinical trials as potential anticancer drugs [26,27] …”

“…Furthermore, their electronic properties can be extensively modified by changing the R groups. [22,24,25] For example, auranofin (Au(I) complex) and RAPTA-C (Ru(II) complex) are compounds composed of a phosphine fragment and are/were present in the clinical trials as potential anticancer drugs. [26,27] In this article, we report the syntheses, physicochemical characterization, aquation chemistry studies along with DFT calculations, and preliminary in vitro antibacterial activity studies of the novel half-sandwich ruthenium(II) Ru(η 6 -pcymene)Cl 2 Ph 2 PCH 2 N(CH 3 )(CH 2 ) 2 Ph and iridium(III) Ir(η 5 -Cp*)Cl 2 Ph 2 PCH 2 N(CH 3 )(CH 2 ) 2 Ph complexes with phosphine derivative of alkaloid Ph 2 PCH 2 N(CH 3 )(CH 2 ) 2 Ph as a ligand.…”

Mononuclear copper(i) complexes bearing a 3-phenyl-5-(pyridin-4-yl)-1,2,4-triazole ligand: synthesis, crystal structure, TADF-luminescence, and mechanochromic effects

“…In the last decade, color tunable luminescent materials have attracted increasing attention for light emitting devices, sensing devices, solar cells, and artificial photosynthesis. [1][2][3][4][5][6][7] Though there are numerous d transition metal ions in various oxidation states, the ions commonly utilized in these studies are mostly limited to the d 6 , d 8 , and d 10 ions, representative ones of which are Ir(III), [8][9][10][11] Pt(II), [12][13][14] and Zn(II) [15][16][17][18] and Cu(I) ions, [19][20][21][22][23] respectively. Despite the considerable advances in recent decades in the synthesis, radiation efficiency and practical use of luminescent d-metal complexes, the development of industrially relevant devices based on them remains an unsolved problem, primarily due to the high cost and low abundance of traditional heavy-atom-based phosphorescent materials, such as platinum, osmium, or iridium.…”