Synthesis, characterization and stereochemistry of bis(acetylacetonato) diisothiocyanato silane

Narula, Suraj P.; Shankar, Ravi; Kaur, Balwant; Soni, Sajeev

doi:10.1016/s0277-5387(00)86208-7

Cited by 5 publications

References 13 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Aspects of the Energetics of Metal β‐Diketonates and their Derivatives

Zeiger

Liebman

Ponikvar‐Svet

2017

Patai's Chemistry of Functional Groups

View full text Add to dashboard Cite

In this chapter, we will discuss diverse aspects of the energetics of metal β‐diketonates and their derivatives. By “energetics” we mean thermochemical and related studies, and so we include enthalpies of reaction and of formation as well as equilibrium measurements and stability constants. We will also discuss the gain or loss of an electron, and therefore consider ionization potentials, electron affinities, and electrochemical potentials. By metal β‐diketonates and derivatives we mean, most generally, species with a substructure of the type [M(dik) n ], where dik (β‐diketonato) is an organic monovalent anion of structure (RC(X)C(R 1 )C(O)R 2 ) − and M is an arbitrary metal. For completeness and additional insights, in this chapter we will also consider M to be virtually all elements (nonmetal, metalloid, or metal), and eventually we will include hydrogen.

show abstract

Aspects of the Energetics of Metal β‐Diketonates and their Derivatives

Zeiger

Liebman

Ponikvar‐Svet

2017

Patai's Chemistry of Functional Groups

View full text Add to dashboard Cite

show abstract

ChemInform Abstract: Synthesis, Characterization and Stereochemistry of Bis(acetylacetonato) diisothiocyanato Silane.

et al. 1992

View full text Add to dashboard Cite

show abstract

Hexacoordinate Silicon(IV) Complexes Containing Thiocyanato‐N Ligands — Syntheses, Structural Characterization, and Computational Studies

Seiler

Bertermann

Buggisch

et al. 2003

Zeitschrift anorg allge chemie

View full text Add to dashboard Cite

The hexacoordinate silicon(IV) complexes [NEt4]2[Si(NCS)6] (2), [K(18‐crown‐6)]2[Si(NCS)6]·2CH3CN (3·2CH3CN), and cis‐[(acac)2Si(NCS)2] (cis‐4; acac = acetylacetonato‐O, O) were synthesized, starting from Si(NCS)4 (1). Compounds 1, 2, 3·2CH3CN, and cis‐4 were structurally characterized in the solid state (13C, 15N (cis‐4 only), and 29Si MAS NMR; crystal structure analyses) and in solution (1H, 13C, and 29Si NMR; cis‐4 only). The experimental investigations were complemented by computational studies (RI‐MP2 geometry optimizations of 1, [Si(NCS)6]2—, cis‐4, and trans‐4; calculations of the 29Si NMR chemical shifts using the optimized structures).

show abstract

Synthesis, characterization and stereochemistry of bis(acetylacetonato) diisothiocyanato silane

Cited by 5 publications

References 13 publications

Aspects of the Energetics of Metal β‐Diketonates and their Derivatives

Aspects of the Energetics of Metal β‐Diketonates and their Derivatives

ChemInform Abstract: Synthesis, Characterization and Stereochemistry of Bis(acetylacetonato) diisothiocyanato Silane.

Hexacoordinate Silicon(IV) Complexes Containing Thiocyanato‐N Ligands — Syntheses, Structural Characterization, and Computational Studies

Contact Info

Product

Resources

About