2005
DOI: 10.1016/j.jorganchem.2005.05.016
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Synthesis, characterization, reactivity and theoretical studies of ruthenium carbonyl complexes containing ortho-substituted triphenyl phosphanes

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Cited by 36 publications
(18 citation statements)
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“…The hemilabile phosphine-ether ligand and its Ru(II) complexes also have received much attention due to their wide-range of utility in homogeneous catalysis [16][17][18]. Studies of the coordination chemistry of the Ru(II) complexes in particular containing hemilabile phosphine-ether ligands are useful in understanding the catalytic activity of this class of compounds.…”
Section: Introductionmentioning
confidence: 99%
“…The hemilabile phosphine-ether ligand and its Ru(II) complexes also have received much attention due to their wide-range of utility in homogeneous catalysis [16][17][18]. Studies of the coordination chemistry of the Ru(II) complexes in particular containing hemilabile phosphine-ether ligands are useful in understanding the catalytic activity of this class of compounds.…”
Section: Introductionmentioning
confidence: 99%
“…Replacing the PPh 3 promising results in various alkene hydroformylation reactions. We recently observed that the o-alkyl substituents have significant effects on the activity and selectivity in the rhodium and ruthenium catalyzed hydroformylation of propene [11,12]. However, the Rh and Ru complexes of these ligands could not be crystallized and sometimes were found to be unstable in solution.…”
Section: Introductionmentioning
confidence: 99%
“…The following dinuclear palladium complexes were prepared: di-l-chlorodichlorobis(o-methylphenyldiphenylphosphane)di-palladium (6), di-l-chlorodichlorobis(o-ethylphenyldiphenylphosphane)dipalladium (7), di-l-chlorodichlorobis(o-isopropylphenyldiphenylphosphane)di-palladium (8), di-l-chlorodichlorobis-(o-cyclohexylphenyldiphenylphosphane)di-palladium (9) and di-l-chlorodichlorobis(o-phenylphenyldiphenylphosphane)di-palladium (10). We also prepared the following mononuclear complexes: dichlorobis(o-methylphenyldiphenylphosphane) palladium (11), dichlorobis(o-ethylphenyldiphenylphosphane) palladium (12), dichlorobis(o-isopropylphenyldiphenylphosphane) palladium (13), dichlorobis(ocyclohexylphenyldiphenylphosphane) palladium (14) and dichlorobis(o-phenylphenyldiphenylphosphane) palladium (15). The X-ray structures of 6, 8-12 and 14 were also obtained.…”
Section: Introductionmentioning
confidence: 99%
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“…(2)). Monometallic complexes containing metal carbonyl fragments with [P,S] chelation of (2-thiomethylphenyl)diphenylphosphine ligands have been well documented [26][27][28], but only one complex containing iron tricarbonyl ligated to a neutral [P,S] ligand has been described previously [29]. Compound 3 displays three absorption bands (1996, 1928 (shoulder), and 1905 cm À1 ) in the carbonyl region of the IR spectrum.…”
Section: Syntheses and Spectral Propertiesmentioning
confidence: 99%