Synthesis, characterization, structure and redox property of azo-amido and orthometallated azo-imine platinum(II) complexes

A sustainable strategic approach for N-alkylation of amines with activation of alcohols triggered via a hydrogen auto-transfer reaction using a Pd(ii) complex: evidence for metal–ligand cooperativity

“…The mixed metal–ligand charge transfer transitions are attributed to the low energy absorption bands in the 560–700 nm region. 98…”

“…The shift in ν NvN confirms the coordination of the azo nitrogen atom to the metal center due to back donation of the electron density from the metal to the ligand. 98 The electronic characteristics of the compound were further examined using UV-Vis spectroscopy. Fig.…”

“…The mixed metal-ligand charge transfer transitions are attributed to the low energy absorption bands in the 560-700 nm region. 98 X-ray crystal structure Suitable sized and good diffraction quality crystals of the complex 1 were obtained by the slow evaporation technique (in CH 2 Cl 2 :toluene). The geometry and molecular structure of the complex were determined by single crystal X-ray crystallography.…”