Synthesis, crystal structure and non-linear optical properties of boronates derivatives of salicylideniminophenols

Muñoz, Blanca M.; Santillán, Rosa; Rodríguez, Mario; Méndez, José Manuel Gómez y; Romero, M.; Farfán, Norberto; Lacroix, Pascal G.; Nakatani, Keitaro; Ramos‐Ortíz, Gabriel; Maldonado, José Luis

doi:10.1016/j.jorganchem.2008.01.032

Cited by 37 publications

(11 citation statements)

References 54 publications

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“…Complexes 1 – 5 are soluble in ethyl acetate, chloroform, and CH 2 Cl 2 . The microwave‐assisted synthesis, resulted to be ten times faster and cheaper than the traditional solution via …”

Section: Resultsmentioning

confidence: 99%

Fluorescent boron Schiff bases dyes for staining silk fibroin: Green synthesis, structural characterization, DFT, and photophysical properties

Molina‐Paredes

Jiménez-Pérez

Lara‐Cerón

et al. 2018

Applied Organom Chemis

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Five novel organoboron complexes were synthesized in just 15 min via microware irradiation, by one pot multicomponent reactions between diverse aryl aldehydes with benzoylhydrazide, or 4-nitrobenzoylhidrazine and diphenyl boronic acid, in a 1:1:1 ratio in benzene. The products were characterized by 1 H, 13 C, 11 B NMR, UV, IR, spectroscopy and high-resolution mass spectrometry (HRMS). The molecular structure was also determined by singlecrystal X-ray diffraction for two complexes, which showed the tetra-coordination of the boron atoms giving rise to distorted tetrahedral molecular geometry with a strong intermolecular C-H···π interactions. In spite of the low quantum yields exhibited by the series in solution, some complexes stained uniformly the silk fibroins emitting enough fluorescence to allow its characterization by confocal microscopy. Boron as chelate center of the five complexes resulted not to be toxic for B16F10 cells, these compounds are appropriate for their used in medical applications.

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Section: Resultsmentioning

confidence: 99%

Fluorescent boron Schiff bases dyes for staining silk fibroin: Green synthesis, structural characterization, DFT, and photophysical properties

Molina‐Paredes

Jiménez-Pérez

Lara‐Cerón

et al. 2018

Applied Organom Chemis

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“…The investigation of the NLO properties of the molecules 11-15 (Chart 2) reported previously was part of an important collaboration initiated 15 years ago with a group of chemists of Mexico, wishing to renew their scientific collaborations outside the American sphere, in the perspective of finding applications of organo-boron [32][33][34] and tin [35][36][37] derivatives in optics. Altogether, there were only few boron and tin based NLO molecules reported in the literature.…”

Section: Schiff-bases Complexes Of Boron and Tinmentioning

confidence: 99%

Second-order nonlinear optics in coordination chemistry: An open door towards multi-functional materials and molecular switches

Lacroix

Malfant

Lepetit

2016

Coordination Chemistry Reviews

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100

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“…Complex [MoO 2 (acac) 2 ] was freshly synthesized as previously described [12]. The Schiff base ligands H 2 L 1-4 were prepared according to the literature procedures [13,14,15,16]. The physical and spectroscopic properties of these compounds are given in the SI.…”

Section: Experimental Partmentioning

confidence: 99%

Substituent effects on solvent-free epoxidation catalyzed by dioxomolybdenum(VI) complexes supported by ONO Schiff base ligands

Wang

Guerrero

Merecias

et al. 2015

Inorganica Chimica Acta

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effects on solvent-free epoxidation catalyzed by dioxomolybdenum(VI) complexes supported by ONO Schiff base ligands, Inorganica Chimica Acta (2015), doi: http://dx. AbstractMolybdenum complexes of type [MoO 2 L] n (L= tridentate ONO Schiff base ligands based on the salicylidene-2-aminophenolato structure) have been synthesized and used as catalysts for the solvent-free epoxidation of olefins. The effect of donor (diethylamino) and/or acceptor (nitro) substituents has been studied. 2 Graphical abstract Highlights • Synthesis and characterization of substituted tridentate Schiff-base dioxomolybdenum complexes • These [MoO 2 L] 2 complexes are active epoxidation catalysts • Analysis of the molecular structures • Electronic effect of donor and acceptor substituents on the catalytic activity Keywords molybdenum / tridentate Schiff-base ligands / epoxidation / organic solvent-free / catalysis 3

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Synthesis, crystal structure and non-linear optical properties of boronates derivatives of salicylideniminophenols

Cited by 37 publications

References 54 publications

Fluorescent boron Schiff bases dyes for staining silk fibroin: Green synthesis, structural characterization, DFT, and photophysical properties

Fluorescent boron Schiff bases dyes for staining silk fibroin: Green synthesis, structural characterization, DFT, and photophysical properties

Second-order nonlinear optics in coordination chemistry: An open door towards multi-functional materials and molecular switches

Substituent effects on solvent-free epoxidation catalyzed by dioxomolybdenum(VI) complexes supported by ONO Schiff base ligands

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