2010
DOI: 10.1007/s11224-010-9649-z
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Synthesis, crystal structure, and properties of a three-dimensional coordination polymer [Cd(PMP)2] n

Abstract: A new Cd(II) coordination polymer, [Cd(PMP) 2 ] n (1) [PMP = 1-phenyl-3-methyl-5-pyrazolone], has been synthesized by the reaction of Cd(CH 3 COO) 2 Á2H 2 O with PMP and characterized by elemental analysis, IR spectrum, fluorescence spectrum, UV-vis spectrum, TG-DTA, and electrochemical analysis. Single crystal X-ray diffraction reveals that the complex has a three-dimensional network. Each PMP acts as bidentate bridging ligand and each Cd(II) center is surrounded by two O atoms and two N atoms from four diffe… Show more

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Cited by 8 publications
(4 citation statements)
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“…Synthesis, characterization, and X-ray single crystal structure determination of a new 3D Cd(II) coordination polymer, [Cd(PMP) 2 ] n (PMP = 1-phenyl-3-methyl-5-pyrazolone) is reported in the experimental paper by Xu et al [270]. Each Cd(II) is four-coordinated with a distorted tetrahedral geometry and linked by four PMP molecules that act as bidentate bridging ligands.…”
Section: Issuementioning
confidence: 99%
“…Synthesis, characterization, and X-ray single crystal structure determination of a new 3D Cd(II) coordination polymer, [Cd(PMP) 2 ] n (PMP = 1-phenyl-3-methyl-5-pyrazolone) is reported in the experimental paper by Xu et al [270]. Each Cd(II) is four-coordinated with a distorted tetrahedral geometry and linked by four PMP molecules that act as bidentate bridging ligands.…”
Section: Issuementioning
confidence: 99%
“…Just like other ligands containing N and O donors, PMP can display several different coordination modes15–19. For many years, we have been interested in the construction of metal complexes derived from PMP, and synthesized some PMP complexes such as [Zn(PMP) 2 Cl] n ,15 [Cd(PMP) 2 ] n ,16 and [Cd 2 (PMP) 2 Cl 4 ] n 17. As a continuation of our work, we have prepared another novel organomercury compound, [Hg 2 (PMP)Cl 2 ] 2 · DMF ( 1 ).…”
Section: Introductionmentioning
confidence: 99%
“…The research of compounds containing these cations, their ionic antagonists (like other alkaline metals) with anions existing in body fluids is thus of great importance, as they affect the sodium-potassium pump. In addition, recently, an increasing interest is put on construction of dinuclear, multinuclear and polymeric coordination compounds [24][25][26][27] created by self-assembly [28] of the components [29][30][31][32].…”
Section: Introductionmentioning
confidence: 99%