Synthesis, crystal structure and thermal behavior of magnesium 5,5′-bistetrazole-1,1′-diolate hexahydrate complex

Wang, Xiaojun; Wang, Na; Yang, Yongrong; Guoliang, Jin; Zhouting, Li; Wang, Xia; Zhiyan, Lu

doi:10.1080/07370652.2020.1762801

Cited by 5 publications

(5 citation statements)

References 23 publications

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“…5,6 Secondly, more researchers are dedicating their efforts to exploring its derivatives and potential applications. 7–10 Thirdly, attention is being paid to the thermal decomposition process of TKX-50 and its explosive performance in practical scenarios. 11–32 Finally, there is significant interest in understanding the crystal structure and properties of TKX-50.…”

Section: Introductionmentioning

confidence: 99%

Theoretical study on intra-molecule interactions in TKX-50

Yang,

Li,

Zhou

et al. 2023

Phys. Chem. Chem. Phys.

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Section: Introductionmentioning

confidence: 99%

Theoretical study on intra-molecule interactions in TKX-50

Yang,

Li,

Zhou

et al. 2023

Phys. Chem. Chem. Phys.

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“…As can be observed, RDX is orthorhombic with the space group Pbca , while HMX and CL-20 is monoclinic with space groups P 2 1 / c and P 2 1 / a , respectively, revealing the distinct crystal nature, whose specific diffraction maximums are indexed and reported in the foregoing work, with JCPDS card no. 46-RDX: 1619, HMX: 45-1539, and CL-20: 50-2045 . With regard to the core–shell composites whose energetic crystals were coated with the CNF, the representative diffraction peaks of the explosive crystals were retained undamaged, manifesting that a satisfactory crystallinity is preserved in the energetic composite products.…”

Section: Resultsmentioning

confidence: 99%

Biomimetic-Inspired One-Step Strategy for Improvement of Interfacial Interactions in Cellulose Nanofibers by Modification of the Surface of Nitramine Explosives

et al. 2021

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Recently, a burgeoning category of biocompatible botanically derived nanomaterial cellulose nanofibers (CNFs) has captured tremendous attention on account of its entangled nanostructured network, natural abundance, and outstanding mechanical properties. Biomimetically inspired by the superior properties of CNFs, this paper examined them as the coating material to cover cyclotrimethylenetrinitramine (RDX), cyclotetramethylenetetranitramine (HMX), and hexanitrohexaazaisowurtzitane (CL-20) via a facile water suspension method and the ultrasonic technology. The core−shell structure and the composition of energetic crystal@CNF were examined through scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy analyses. The obtained outcomes demonstrated that the dispersibility of the CNF enhanced favorably upon covering the surface of explosive crystals; the interfacial contact ability between CNFs and energetic crystals was also manifested to be increased, which could be ascribed to the interfacial interaction of hydrogen bonds and the electrostatic force of self-assembly. In addition, the stable crystalloid construction of β-HMX and ε-CL-20 has been preserved positively in the preparation process. In comparison with raw explosives, the thermal stability and sensitivity performances of the core−shell structure composites were outstanding. Accordingly, this work demonstrated the rewarding application of coating CNFs uniformly on the surface of energetic crystals, ulteriorly offering a potential fabrication strategy for the embellishment of high-explosive crystals.

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“…In differential thermal analysis (DTA), the sample temperature is compared to the temperature of the reference material. It is always recommended to use both TG and DTA to understand mass change in relation to temperature [35]. The TGA trace of BLSOD, shown in Fig.…”

Section: Thermal Analysesmentioning

confidence: 99%

Investigations on the synthesis and growth and structural, spectral, optical, mechanical and thermal properties of non-linear optical single crystals of Bis-L-Seriniumoxalate Dihydrate (BLSOD)

Hidayathullah¹,

Samuel²,

Chithambaram³

et al. 2023

JOR

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From the raw materials L-Serine and oxalic acid, the product Bis-LSeriniumoxalatedehydrate(BLSOD) was created. By using a slow evaporation process, the individual BLSOD crystals were produced from aqueous solution. According to single crystal X-ray Diffraction investigations, the structure of the produced crystal is monoclinic. The existence of different functional groups and the chemical environment present in the synthesised material were qualitatively determined through the use of Fourier Transform Infra-Red (FTIR) and proton nuclear magnetic resonance (H1NMR) spectrum studies. The crystal's transparency in the visible and near-infra-red areas was confirmed by UV-Visible-Near infrared and photoluminescence spectrum tests, which also looked at the material's viability for device construction. To determine the crystal's machinability, the mechanical properties of the material were carefully examined using Vicker's hardness research. Thermal investigations such as Thermo gravimetric (TGA) and Differential thermal analysis (DTA) have shown the thermal stability of BLSOD and the phases of weight losses. As a function of frequency and temperature, the dielectric constant and dielectric loss of grown crystals were determined. The Kurtz-Perry powder test was used to check both the second harmonic generation (SHG) and then the NLO property of the material.

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Synthesis, crystal structure and thermal behavior of magnesium 5,5′-bistetrazole-1,1′-diolate hexahydrate complex

Cited by 5 publications

References 23 publications

Theoretical study on intra-molecule interactions in TKX-50

Theoretical study on intra-molecule interactions in TKX-50

Biomimetic-Inspired One-Step Strategy for Improvement of Interfacial Interactions in Cellulose Nanofibers by Modification of the Surface of Nitramine Explosives

Investigations on the synthesis and growth and structural, spectral, optical, mechanical and thermal properties of non-linear optical single crystals of Bis-L-Seriniumoxalate Dihydrate (BLSOD)

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