Synthesis, crystal structure, Hirshfeld surface analysis, spectroscopic studies, electric and dielectric properties of the new Hg(II) complex with N,N-dimethy-p-toluidine ligand: [C9H14N]HgCl3

Hajbi, Mariem; Abdi, M.; Loukil, M.

doi:10.1007/s11581-017-2361-x

Cited by 4 publications

(2 citation statements)

References 59 publications

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“…This approach facilitates the identification of connections between the electrochemical system parameters and traits of the impedance elements.The equivalent circuit configuration forAg0.2Na0.8FeP2O7consists of resistance, capacitance, and fractal capacitance ( as shown in the inset of Fig. 9 The CPE impedance is given by the subsequent relationship [32]:…”

Section: Impedance Spectroscopy Resultsmentioning

confidence: 99%

Investigation into the Crystal Structure, Hirshfeld Surface Analysis, and Electrical Transport Conduction of theAg0.2Na0.8FeP2O7compound

Nasri,

Felhi,

Almutairi

et al. 2024

Preprint

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In this study, a new diphosphate compound, Ag0.2Na0.6FeP2O7, was synthesized using a solid-state reaction method and extensively studied using various techniques. The compound's structure was confirmed through X-ray diffraction analysis, revealing a single-phase monoclinic structure with the P21/C space group. The electrical behavior of the compound was investigated, and its conductivity followed Jonscher's universal law. The correlated barrier hopping (CBH) model explained the temperature-dependent ac conductivity and parameter "s" well. The study also explored the contribution of single-polaron and bipolaron hopping to the a.c. conductivity and discussed the ionic conductivity in relation to the structural characteristics of the sample. Overall, this investigation significantly enhances our comprehension of the distinctive electrical properties of Ag0.2Na0.6FeP2O7 and its potential practical applications.

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Section: Impedance Spectroscopy Resultsmentioning

confidence: 99%

Investigation into the Crystal Structure, Hirshfeld Surface Analysis, and Electrical Transport Conduction of theAg0.2Na0.8FeP2O7compound

Nasri,

Felhi,

Almutairi

et al. 2024

Preprint

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“…The 2D fingerprint plots can be decomposed in order to highlight particular atom pair close contacts. This decomposition enables the separation of contributions from different interaction types, which overlap in the full fingerprint [24]. The surface has been mapped over a dnorm range of −0.…”

Section: Resultsmentioning

confidence: 99%

Deciphering the Structural Characterization, Hirshfeld Surface Analysis, Raman Studies, and Temperature-Dependent Magnetodielectric Properties of BiMn2O5

et al. 2021

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We investigate the structural, Hirshfeld surface, magnetic, and magnetodielectric properties of BiMn2O5. The sample can be indexed with an orthorhombic phase associated with space group Pbam, with crystallographic parameters a = 7.54946 Å, b = 8.54962 Å and c = 5.753627 Å. The Hirshfeld surface analysis, associated with 2D fingerprint plots, was used to visualize and explore the significant intermolecular interactions in the crystal structure quantitatively. The Raman spectra, measured from 6 to 300 K in a frequency range between 250 and 750 cm−1, exhibit good agreement between the SHELL model calculations and the experimental measurement of the proximity of the phonon frequencies for our sample. Furthermore, magnetic measurements show that BiMn2O5 becomes antiferromagnetic below the Néel temperature (TN)—the temperature above which an antiferromagnetic material becomes paramagnetic (TN = 31 K). The relaxation at intermediate temperatures (200–300 K) can be attributed to the polar jump process at two charge transfer sites between the Mn3+ and Mn4+ ions, which, in combination with the special arrangement of the Mn3+/Mn4+ ions, is likely to produce the strong intrinsic magnetodielectric effect (MD) in the same temperature range.

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Synthesis, structural characterization and electrical conduction mechanism of the new organic–inorganic complex: ([(C3H7)4N]FeCl4)

Brahim

Gzaiel

Oueslati

et al. 2019

Materials Research Bulletin

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Synthesis, crystal structure, Hirshfeld surface analysis, spectroscopic studies, electric and dielectric properties of the new Hg(II) complex with N,N-dimethy-p-toluidine ligand: [C9H14N]HgCl3

Cited by 4 publications

References 59 publications

Investigation into the Crystal Structure, Hirshfeld Surface Analysis, and Electrical Transport Conduction of theAg0.2Na0.8FeP2O7compound

Investigation into the Crystal Structure, Hirshfeld Surface Analysis, and Electrical Transport Conduction of theAg0.2Na0.8FeP2O7compound

Deciphering the Structural Characterization, Hirshfeld Surface Analysis, Raman Studies, and Temperature-Dependent Magnetodielectric Properties of BiMn2O5

Synthesis, structural characterization and electrical conduction mechanism of the new organic–inorganic complex: ([(C3H7)4N]FeCl4)

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