Synthesis, Crystal Structures, Photocatalysis for Rhodamine B Degradation of a Organobismuth (V) Dithiocarbamate Polymer [PhBiS2CN(C2H5)2Cl]n

Photoactive metal–organic frameworks (MOFs) have lately emerged as a class of crystalline porous materials, which provides an advanced platform to develop catalysts for the photocatalytic decolorization of wastewater. Controllable integration of pure MOFs into other active materials creates fabrication protocols for new multifunctional hybrids with superior photocatalytic properties for dye degradation into individual components, and the calcination of transition‐metal MOF precursors affords a convenient and practical route for preparation of nanosized photocatalysts with novel structures and good purity. Although the application of pure MOFs for organic pollutant decomposition has been reviewed previously, there have been significant advances in diverse MOF‐based composites and their derivatives for dye degradation, which have rarely been reviewed. This review aims to fill this gap and discuss the various influencing factors, the reaction kinetics, and mechanisms of dye degradation, considering the period from 2014 to 2016. Finally, the challenges and outlooks for dye decomposition by MOF‐based materials are suggested.

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Photocatalytic Decontamination of Wastewater Containing Organic Dyes by Metal–Organic Frameworks and their Derivatives

Yuan

Zhang

et al. 2016

ChemCatChem

236

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Rhodamine B Adsorptive Removal and Photocatalytic Degradation on MIL-53-Fe MOF/Magnetic Magnetite/Biochar Composites

Navarathna

Dewage

Karunanayake

et al. 2019

J Inorg Organomet Polym

120

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Synthesis, Structure and Photocatalytic Dye Degradation Ability of Co(II)-Based Coordination Polymers

Zuo

Fan

Yang

et al. 2019

J Inorg Organomet Polym

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Synthesis, Crystal Structures, Photocatalysis for Rhodamine B Degradation of a Organobismuth (V) Dithiocarbamate Polymer [PhBiS2CN(C2H5)2Cl]n

Cited by 10 publications

References 26 publications

Photocatalytic Decontamination of Wastewater Containing Organic Dyes by Metal–Organic Frameworks and their Derivatives

Photocatalytic Decontamination of Wastewater Containing Organic Dyes by Metal–Organic Frameworks and their Derivatives

Rhodamine B Adsorptive Removal and Photocatalytic Degradation on MIL-53-Fe MOF/Magnetic Magnetite/Biochar Composites

Synthesis, Structure and Photocatalytic Dye Degradation Ability of Co(II)-Based Coordination Polymers

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