2013
DOI: 10.1016/j.jcrysgro.2012.01.057
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Synthesis, growth and characterisation of tetrathiourea cadmium tetrathiocyanato zincate single crystals

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Cited by 4 publications
(3 citation statements)
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“…Etch patterns observed on crystal surface provides detailed information of the growth process and growth mechanism of the crystal. 24 In present investigation, etching studies were carried out for PCLQI crystal using methanol-acetonitrile (3 : 1) as etchant for a time period of 15 s and 30 s. The crystal surface was examined using a Carl ziess optical microscope in reection mode. The surface micrograph of as grown crystal is shown in Fig.…”
Section: Chemical Etching Studiesmentioning
confidence: 99%
“…Etch patterns observed on crystal surface provides detailed information of the growth process and growth mechanism of the crystal. 24 In present investigation, etching studies were carried out for PCLQI crystal using methanol-acetonitrile (3 : 1) as etchant for a time period of 15 s and 30 s. The crystal surface was examined using a Carl ziess optical microscope in reection mode. The surface micrograph of as grown crystal is shown in Fig.…”
Section: Chemical Etching Studiesmentioning
confidence: 99%
“…In fact, considerable efforts have been made to combine thiourea with various interesting inorganic matrices to produce materials having a noncentrosymmetric cell, large polarizability, and a strong nonlinear optical coefficient. When thiourea is combined with inorganic matrix it creates a semiorganic complex which has high optical nonlinearity and chemical flexibility of organics with the physical ruggedness of inorganics [11][12][13]. Ligands like thiourea and thiocyanate with S and N donors are capable of combining with metal to form stable complexes through coordinated bonds.…”
Section: Introductionmentioning
confidence: 99%
“…Organometallic coordination complexes have the potential of combining the high optical nonlinearity and structural flexibility of organic materials with the thermal and mechanical stability of inorganic materials [3,4]. Also in organometallic coordination complexes, the metal-ligand bonding is expected to show large molecular hyperpolarisability because of the transfer of electron density between the metal atom and the conjugated ligand system [5]. Bimetallic thiocyanates compounds having the chemical formula AB(SCN) 4 ( ZnCd(SCN) 4 , MnHg(SCN) 4 , Cd Hg(SCN) 4 , MnHg(SCN) 4 etc), have attracted a great deal of attention for their unique characteristics.…”
Section: Introductionmentioning
confidence: 99%