Synthesis of 1,1-bis(methoxy-NNO-azoxy)-3,3,3-trinitropropane from 1,1-bis(methoxy-NNO-azoxy)ethene and nitroform

Abstract

A reaction of 1,1 bis(methoxy NNO azoxy)ethene with nitroform at ~20 °C gave 1,1 bis (methoxy NNO azoxy) 3,3,3 trinitropropane.

Quantum chemical investigation of the 1‐methyl‐ and 1‐neopentyl‐2‐methoxydiazene‐1‐oxides thermal decomposition mechanisms

“…[ 5–9 ] Some new ADOs have been proposed as components of EM, including those containing other energy‐intensive groups. [ 10–17 ]…”

“…[5][6][7][8][9] Some new ADOs have been proposed as components of EM, including those containing other energy-intensive groups. [10][11][12][13][14][15][16][17] Thermal stability is one of the most important characteristics of potential components of energy materials. Therefore, already at the initial stage of work with ADO in the Institute of Problems of Chemical Physics of the Russian Academy of Sciences, one of the authors of this article (I.N.…”

3-Ethoxy-2,2-bis(methoxy-NNO-azoxy)propan-1-ol. Synthesis and X-ray diffraction analysis

“…9-16 Thus, recently synthesized 1,1 bis(methoxy NNO azoxy)ethene (1) 16 turned out to be useful for the introduction of the 2,2 bis(methoxy NNO azoxy)ethyl group into various compounds by the Michael reaction. [16][17][18][19] The key intermediate for the synthesis of 1,1 bis (methoxy NNO azoxy)ethene (1) is 2,2 bis(methoxy NNO azoxy)ethanol (2), 16 which is widely used in the other transformations. 16,18,[20][21][22] Alcohol 2 could be prepared 16,20 by oxymethylation of bis(methoxy NNO azoxy)methane (3) (Scheme 1).…”