Synthesis of 4-tert-butylperoxy-4-methylpentan-2-one and 3-tert-butylperoxy-3-methylbutanoic acid

New epoxide-containing peroxides have been synthesized via the interaction between epichlorohydrin and ditertiary -hydroxyalkyl peroxides. The effect of reaction conditions on both the yield and composition of the reaction products has been established. Through the reactions of either the synthesized epoxide-containing peroxides with 1,2;3,4-di-O-isopropylidene--D-galactopyranose or 6-O-glycidyl-1,2;3,4-di-O-isopropylidene--D-galactopyranose with the -hydroxyalkyl peroxides, new peroxide derivatives with ditertiary and primary-tertiary peroxide groups have been synthesized successfully. The decomposition of the developed substances has been studied by complex thermal analysis and the kinetic parameters of the thermolysis have been determined.

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Synthesis of 4-tert-butylperoxy-4-methylpentan-2-one and 3-tert-butylperoxy-3-methylbutanoic acid

Cited by 2 publications

References 7 publications

ChemInform Abstract: Synthesis of 4‐tert‐Butylperoxy‐4‐methylpentan‐2‐one and 3‐tert‐Butylperoxy‐3‐methylbutanoic Acid.

ChemInform Abstract: Synthesis of 4‐tert‐Butylperoxy‐4‐methylpentan‐2‐one and 3‐tert‐Butylperoxy‐3‐methylbutanoic Acid.

Synthesis of Epoxyperoxides and Peroxide Derivatives of -D-Galactopyranose Based Thereon

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