Synthesis of an Organotin Oligomer Containing a Heptanuclear Tin Phosphonate Cluster by Debenzylation Reactions:  X-ray Crystal Structure of {Na6(CH3OH)2(H2O)}- {[(BzSn)3(PhPO3)5(μ3-O)(CH3O)]2Bz2Sn}·CH3OH

Song, Shuyan; Ma, Jian‐Fang; Yang, Jin; Gao, and Li-Li; Su, Zhong‐Min

doi:10.1021/om061015u

Cited by 47 publications

(20 citation statements)

References 50 publications

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“…In comparison to the data reported for other phenylphosphonate derivatives (Song et al, 2007;Chunlin et al, 2008;Shankar et al, 2011), we suggest the following assignments for the compound. The bands located at 1174 s, 1112 s, 1062 s cm -1 are assigned to the stretching vibrations of the PO 3 groups.…”

Section: Resultssupporting

confidence: 78%

Synthesis, characterisation and crystal structure of [(CH3)2CH]2NH2(PhPO3H)2SnPh3

Diop

Molloy³

et al. 2012

Main Group Metal Chemistry

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The title compound, [(CH 3) 2 CH] 2 NH 2+ • [(PhPO 3 H) 2 SnPh 3 ]-, has been synthesised and its structure determined by spectroscopies (IR, RMN and M ö ssbauer) and single crystal X-ray crystallography. The M ö ssbauer spectroscopy data for the title compound (QS = 3.50 mm s-1) are in accordance with the trans O 2 SnC 3 geometry at tin atom. The SnPh 3 residue is axially coordinated by two monodentate [PhPO 3 H]-anions, leading to a trigonal-bipyramidal geometry around the tin atom. The anions [(PhPO 3 H) 2 SnPh 3 ]-are linked by pairs of O-H … O interaction, forming an infinite chain. In the crystal, neighbouring chains are linked by hydrogen bonds N-H … O via the cation [(CH 3) 2 CH] 2 NH 2+ forming a three-dimensional network.

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Section: Resultssupporting

confidence: 78%

Synthesis, characterisation and crystal structure of [(CH3)2CH]2NH2(PhPO3H)2SnPh3

Diop

Molloy³

et al. 2012

Main Group Metal Chemistry

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“…In comparison with the data reported for other phenylphosphonates adducts or derivatives (Adair et al, 2003;Song et al, 2007;Chunlin et al, 2008;De Barros et al, 2010;Shankar et al, 2011), we suggest the following infrared band assignments to be made for the compound. The bands located at 1170 s, 1120 s and 1083 s for Cy 2 NH 2 (PhPO 3 H) 2 SnMe 3 ( 2 ) and 1135 s, 1102 s and 1056 s for Bu 2 NH 2 (PhPO 3 H) 2 SnPh 3 ( 3 ) are assigned to the stretching vibrations of the PO 3 groups.…”

Section: Spectroscopic Characterization Of Cy 2 Nh 2 (Phpo 3 H) 2 Snmsupporting

confidence: 77%

“…These triphenyltin(IV) or trimethyltin(IV) derivatives or complexes exist as monomers or polymers with a fivecoordinated tin(IV) atom. Several papers dealing with organotin(IV) chemistry and the coordinating ability of phosphonates have been reported (Raymond et al, 1992;Song et al, 2007;Chunlin et al, 2008;De Barros et al, 2010;Shankar et al, 2011). The X-ray structure of a tetragonal form of [SnMe 3 PhPO 3 H] n has been reported by Molloy et al (1981).…”

Section: Introductionmentioning

confidence: 99%

Synthesis, spectroscopic characterization and crystal and molecular structures of phenylphosphonato SnR3 (R=Ph, Me) derivatives

Diop¹,

Diop²,

Kociok‐Köhn³

et al. 2013

Main Group Metal Chemistry

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Four new phenylphosphonato SnR 3 (R = Ph, Me) derivatives have been synthesized and characterized by infrared and M ö ssbauer spectroscopy. The structure of catena-poly[PhPO 3 HSnMe 3 ] n has been determined by single-crystal X-ray diffraction analysis. The Sn IV atoms are five-coordinated in all compounds, with the SnC 3 O 2 framework in a trans trigonal bipyramidal arrangement and the PhPO 3 H -anions being in axial positions. The molecular structure of [PhPO 3 HSnMe 3 ] n is arranged as a one-dimensional coordination polymer in which planar SnMe 3 groups are axially bridged by -O-P-O-linkages of the PhPO 3 H -ligand. Neighboring chains are linked via O-H … O hydrogen bond interactions, generating a layered structure.In the R 2 NH 2 (PhPO 3 H) 2 SnR′ 3 (R = Cy, Bu; R′ = Ph, Me), the SnPh 3 or SnMe 3 residue is axially coordinated by two monodentate PhPO 3 H -. The role of the dialkylammonium cation, R 2 NH 2 + , is crucial in the lattice building via a hydrogen bond network. These hydrogen bonds contribute to the crystal stability and compactness and result in a three-dimensional arrangement. The aqua complex PhPO 3 (SnPh 3 ) 2 . 2H 2 O has a discrete structure and the anion PhPO 3 2-behaves as a bidentate ligand.

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“…Comparing with the carboxylate group, the phosphate group contains three potential coordination of oxygen atoms. So, the phosphate group can coordinate both as a monoanionic group and as a dianionic group [14]. We have reported the selfassembly syntheses and crystal structures of triphenyltin(IV) phenylphosphate [15], triorganotin O,Odiisopropylphosphoric [16], and diphenyltin(IV) derivative of phenylphosphoric acid [17].…”

Section: Introductionmentioning

confidence: 99%

Self‐assembly syntheses and crystal structures of dimeric di‐n‐butyltin phosphates containing eight‐membered Sn₂O₄P₂ inorganic ring

Zhang

Wang

et al. 2010

Heteroatom Chemistry

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Two organotin (IV) derivatives, [Bu2‐ Sn(HO3PO‐i‐Pr)2]2 (1) and [Bu2Sn(HO3POPh)2]2 (2), have been prepared by reactions of di‐n‐butyltin oxide with the phenylphosphoric acid and isopropylphosphoric acid, respectively. Characterization of the complexes 1 and 2 was achieved using elemental analysis, IR, NMR (1H, 13C, 31P, and 119Sn) spectroscopy, and X‐ray crystallography diffraction analysis. The X‐ray data reveal that complexes 1 and 2 are dimers containing eight‐membered Sn2O4P2 inorganic ring. Interestingly, complexes 1 and 2 are further linked into 2D network through intermolecular O … Sn weak contacts and OH … O weak hydrogen‐bonding interactions. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:298–303, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20610

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Synthesis of an Organotin Oligomer Containing a Heptanuclear Tin Phosphonate Cluster by Debenzylation Reactions: X-ray Crystal Structure of {Na₆(CH₃OH)₂(H₂O)}- {[(BzSn)₃(PhPO₃)₅(μ₃-O)(CH₃O)]₂Bz₂Sn}·CH₃OH

Abstract: The first organotin phosphonate oligomer composed of alternating heptanuclear tin phenylphosphonate and hexanuclear sodium phenylphosphonate clusters was synthesized by a debenzylation process under solVothermal conditions.

Cited by 47 publications

References 50 publications

Synthesis, characterisation and crystal structure of [(CH3)2CH]2NH2(PhPO3H)2SnPh3

Synthesis, characterisation and crystal structure of [(CH3)2CH]2NH2(PhPO3H)2SnPh3

Synthesis, spectroscopic characterization and crystal and molecular structures of phenylphosphonato SnR3 (R=Ph, Me) derivatives

Self‐assembly syntheses and crystal structures of dimeric di‐n‐butyltin phosphates containing eight‐membered Sn₂O₄P₂ inorganic ring

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Synthesis of an Organotin Oligomer Containing a Heptanuclear Tin Phosphonate Cluster by Debenzylation Reactions: X-ray Crystal Structure of {Na6(CH3OH)2(H2O)}- {[(BzSn)3(PhPO3)5(μ3-O)(CH3O)]2Bz2Sn}·CH3OH

Abstract: The first organotin phosphonate oligomer composed of alternating heptanuclear tin phenylphosphonate and hexanuclear sodium phenylphosphonate clusters was synthesized by a debenzylation process under solVothermal conditions.

Cited by 47 publications

References 50 publications

Synthesis, characterisation and crystal structure of [(CH3)2CH]2NH2(PhPO3H)2SnPh3

Synthesis, characterisation and crystal structure of [(CH3)2CH]2NH2(PhPO3H)2SnPh3

Synthesis, spectroscopic characterization and crystal and molecular structures of phenylphosphonato SnR3 (R=Ph, Me) derivatives

Self‐assembly syntheses and crystal structures of dimeric di‐n‐butyltin phosphates containing eight‐membered Sn2O4P2 inorganic ring

Contact Info

Product

Resources

About

Synthesis of an Organotin Oligomer Containing a Heptanuclear Tin Phosphonate Cluster by Debenzylation Reactions: X-ray Crystal Structure of {Na₆(CH₃OH)₂(H₂O)}- {[(BzSn)₃(PhPO₃)₅(μ₃-O)(CH₃O)]₂Bz₂Sn}·CH₃OH

Self‐assembly syntheses and crystal structures of dimeric di‐n‐butyltin phosphates containing eight‐membered Sn₂O₄P₂ inorganic ring