Synthesis of bimannich base with thiazole and its corrosion inhibition effect on H2S and CO2 at high temperature

Abstract

A bimannich-based TZBM containing a thiazole ring was obtained by synthesis of mannich bases. TZBM featured a stable structure at 260 °C, and corrosion inhibition effect on carbon steel in a gas–liquid environment with Cl− + H2S + CO2 at 180 °C. By analyzing the weight loss of steel exposed to different TZBM concentrations, the coverages of the inhibitor adsorbed on the surfaces were determined, and the results conformed to Langmuir isotherm model. Furthermore, the negative Gibbs free energy indicated that the adsorption was a spontaneous process. Graphical Abstract

Mechanism and anti-corrosion measures of carbon dioxide corrosion in CCUS: A review

“…Coincidentally, Li et al. 104 obtained a bimannich-based TZBM containing a thiazole ring by synthesizing Mannich base, which effectively inhibits the corrosion of containing Cl − +H 2 S + CO 2 environment as illustrated in Figure 10 E. Figure 11 A represent the synthetic of TZBM. The inhibitor molecules adsorbed on the surface block the corrosive medium.…”

“… 103 ) Copyright 2021, Elsevier; (E) (Zhuoke et al. 104 ) Copyright 2021, BMC; (F) (Farhadian et al. 105 ) Copyright 2023, Elsevier; (G) (Guo et al.…”