Synthesis of bimetallic 4-PySI-Pd@Cu(BDC) via open metal site Cu-MOF: Effect of metal and support of Pd@Cu-MOFs in H2 generation from formic acid

Layer‐Wise Titania Growth Within Dimeric Organic Functional Group Viologen Periodic Mesoporous Organosilica as Efficient Photocatalyst for Oxidative Formic Acid Decomposition

“…However, there have been only a few studies successfully employing TiO 2 in photo-oxidation of FA and a few reports are in the catalytic strength of titania for this particular transformation. [9,10] The interest of this reaction has increased in the recent years because of the possibility of developing direct FA fuel cells (DFACs), that can reach high power densities and could be power sources for portable electronic devices. Recently, Ide and co-workers investigated hydrothermal treatment of P25 to selectively convert the amorphous component into crystalline titania, which is deposited between the original anatase and rutile particles to increase the particle interfaces and thus enhanced charge separation for FA photooxidation.…”

“…[8] FA has been recently considered as a potential liquid storage material capable of releasing H 2 under mild conditions via catalytic decomposition process. [9,10] The interest of this reaction has increased in the recent years because of the possibility of developing direct FA fuel cells (DFACs), that can reach high power densities and could be power sources for portable electronic devices. [11,12] On the other hand, FA is one of the major products of biomass processing that has been regarded as a convenient and safe hydrogen storage material because of its nontoxicity, high stability and high H 2 content (4.4 wt %).…”

C‐S cross‐coupling reaction using novel and green synthesized CuO nanoparticles assisted by Euphorbia maculata extract

“…This may be due to their unique characteristics like smaller size, high surface area, high density of defect sites, increased efficiency and selectivity and reusability . Biosynthesized metal nanoparticles have a combination of the two complementary properties: the inorganic properties like mechanical/thermal/structural stability and the properties of organic pendant moieties such as flexibility in solution (like homogeneous catalysts) and therefore, high reactivity of the catalyst . Cross‐coupling reactions have been used as powerful and useful synthetic tools in novel synthetic chemistry .…”

Determination of optimum Pd:Ni ratio for Pd x Ni 100‐ x / CNT s formic acid electrooxidation catalysts synthesized via sodium borohydride reduction method

“…Additionally, geometric and electronic structure of Pd can be optimized by the addition of a second metal . Since Pd is an expensive metal, observing the positive effect of Pd on FAE activity even at very low molar ratio is another advantage provided by Pd‐based bimetallic catalysts . Furthermore, the preparation of Pd‐based bimetallic catalysts in core‐shell structure significantly improves the stability .…”

“…34 Since Pd is an expensive metal, observing the positive effect of Pd on FAE activity even at very low molar ratio is another advantage provided by Pd-based bimetallic catalysts. [35][36][37][38] Furthermore, the preparation of Pd-based bimetallic catalysts in core-shell structure significantly improves the stability. [39][40][41] Although there are many studies on the development of bimetallic catalysts, to our knowledge, they were generally synthesized at equimolar metal ratio.…”