Synthesis of diethylditritiumstannane Et2SnT2, a generator of stannylium cations

The synthesis and topochemical polymerization of o-carborane-based diacetylene macrocycles

“…13 Additionally, carboranes have shown great potential for topochemical polymerization in the field of supramolecular chemistry. The exceptional stability and geometrical properties exhibited by o-carborane in both anionic and neutral forms, along with its unique characteristics such as low nucleophilicity, 14 unparalleled chemical inertness, 15 electron-withdrawing nature through carbon cluster vertex substituents, and adaptable hydrophilicity, have sparked research in developing novel polymeric materials that incorporate boron clusters. [16][17][18][19] Herein, we sought to integrate the properties of a conjugated polymer with porous materials.…”

Radiochemical study of gas-phase reactions of diethylstannyl cations Et2SnT+ with oxygen-containing compounds: II. Reaction of diethylstannyl cations with butanol

“…The procedure for the synthesis of diethyl( 3 H 2 ) stannane was described in [24]. Butan-1-ol of spectroscopic grade was used as substrate.…”