“…Monoterpene-based 1,2-and 1,3-amino alcohols have been demonstrated to be excellent chiral auxiliaries in aw ide range of stereoselective transformations, including intramolecular radical cyclizations, [11] intramolecular [2+ +2] photocycloaddition, [12] and Grignard addition. [13,14] Furthermore,a minodiols, combining the chemical properties of 1,2-and 1,3-amino alcohols derived fromn aturally occurring terpenes, are excellent startingm aterials and catalysts of stereoselectives ynthesis. [15][16][17][18][19][20] Moreover,a minodiols are excellent buildingb locks for the synthesis of 1,3-oxazinesa nd oxazolidines.…”