Synthesis of Glycidyl Ether of Poly(bisphenol-A 1,1′-ferrocene dicarboxylate) and Its Electrochemical Behavior

Abstract

A novel ferrocene-based epoxy compound of the glycidyl ether of poly(bisphenol-A 1,1 -ferrocene dicarboxylate) (GEPBFC) was synthesized and the electrochemical behavior of its films and solutions was investigated by cyclic voltammetry (CV). It was found that the GEPBFC films and solutions present different CV behavior in different solvents and the swelling ability of the solvent is the main factor that affects the CV behavior of GEPBFC films. The kinetic parameters of the film-electrode process, including the surface transfer coefficient, the apparent diffusion coefficient and the standard rate constant in LiClO 4 ethanol solution, were calculated, and the corresponding electrode-process mechanism was discussed.

Tris(2‐aminoethyl)amine‐based ferrocene‐terminated dendrimers as burning rate catalysts for ammonium perchlorate‐based propellant decomposition

“…So, the electrochemical properties of G0, G1 and G2 (0.5 mM) were analyzed in DCM, CHCl 3 and dimethylsulfoxide (DMSO) using Bu 4 NBF 4 (0.10 M) as a supporting electrolyte at various potential scan rates with CV. It was found that the CV curves of G0, G1 and G2 were affected by both solvent polarity and potential scan rate . An increase in polarity of the solvent resulted in the deformation of the peak shapes.…”

Liquid‐crystalline azobenzene‐containing ferrocene‐based polymers: study on synthesis and properties of main‐chain ferrocene‐based polyesters with azobenzene in the side chain

“…PPFD was synthesized via solution polycondensation reaction of PDE with 1,1′‐ferrocenedicarbonyl chloride according to the reported method to produce PPFD. The synthetic procedures were mentioned in our earlier work.…”

Study on the electrochemical, thermal, and liquid crystalline properties of poly(diethyleneglycol 1,1′-ferrocene dicarboxylate)

“…PDEFD was synthesized by solution polycondensation reaction of diethylene glycol with 1,1′-ferrocenedicarbonyl chloride according to the reported method [34]. In typical procedures, 1.5745 g (5.06 mmol) of 1,1′-ferrocenedicarbonyl chloride was dissolved in 10.6 mL freshly distilled THF.…”

“…The electrochemical behavior of ferrocene compounds and ferrocene-based polymers was found to be affected by many factors including the type and the concentration of the supporting electrolyte, the potential scan rate, and also the polarity of the solvent [34,36,[44][45][46].…”