Synthesis of<i>N</i>-(Dimethylsulfamoyl)aldimines, a New Type of Aldimine Derivative

Huisman, M.C.; Have, Ronald ten; Leusen, A. M. Van

doi:10.1080/00397919708003037

Cited by 15 publications

(8 citation statements)

References 14 publications

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“…The ligand H 2 L·2HBr (1,4-di[4(5)-imidazolyl)] benzene dihydrobromide) was synthesized as described in the literature, − for which the details are provided in the Supporting Information. A sample of 85 mg of CuCl 2 ·2H 2 O (0.5 mmol) was dissolved in 125 mL of deionized water and stirred for 15 min.…”

Section: Methodsmentioning

confidence: 99%

Highly CO₂ Selective Microporous Metal-Imidazolate Framework-Based Mixed Matrix Membranes

Ahmadi

Taş

Kılıç

et al. 2017

ACS Appl. Mater. Interfaces

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Microporous metal-imidazolate framework (MMIF), a highly CO selective MOF, was incoporated into a polymeric membrane for separation of CO from CH and N for the first time. MMIF nanoparticles of 50-200 nm were synthesized using the sonication method and dispersed into Matrimid, a commercial polyimide, with MOF loading of 10% and 20% by weight to fabricate mixed matrix membranes (MMMs). Morphology, thermal behavior, and glass transition temperature of the membranes were characterized, and single and mixed gas permeation measurements at 35 °C and 4 bar feed pressure were carried out to reveal their separation performance. Both 10% and 20% MMIF containing Matrimid membranes exhibited enhanced gas permeabilities for all three gases. Contrary to expectations, ideal selectivity of membranes was not improved possibly due to the flexible framework of MMIF. On the other hand, mixed gas permeability measurements showed significant improvement in CO/CH separation factor by 130% and CO/N separation factor by 79% due to competitive adsorption favoring CO.

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Section: Methodsmentioning

confidence: 99%

Highly CO₂ Selective Microporous Metal-Imidazolate Framework-Based Mixed Matrix Membranes

Ahmadi

Taş

Kılıç

et al. 2017

ACS Appl. Mater. Interfaces

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“…Synthesis of N , N ‐(Dimethylsulfamoyl)benzaldimines 1a–c: Compounds 1a – c were synthesized according to a literature procedure 25. The corresponding benzaldehyde (20 mmol) and N , N ‐dimethylsulfamide (2.54 g, 20.5 mmol) were dissolved in toluene (80 mL) and water was azeotropically distilled for 16 h using a Dean–Stark apparatus.…”

Section: Methodsmentioning

confidence: 99%

Synthesis of Enantiopure Benzyl Homoallylamines by Indium‐Mediated Barbier‐Type Allylation Combined with Enzymatic Kinetic Resolution: Towards the Chemoenzymatic Synthesis of N‐Containing Heterocycles

et al. 2010

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Barbier-type indium-mediated allylations of different N,N-(dimethylsulfamoyl)-protected aldimines with a number of allyl bromides followed by high-yielding deprotection afforded allylic amines in good to excellent yields. The racemic amines were then subjected to enzymatic kinetic resolution in order to obtain the corresponding (S)-amines and (R)-amides. When acyl donors with a terminal double bond were applied in the enzymatic kinetic resolution, the product

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“…For the synthesis of the title compound, see: Petersen (1950); Huisman (1997); Have (1997). For a similar structure, see: Gao & Duan (2012).…”

Section: Related Literaturementioning

confidence: 99%

“…The title compound was synthesized according to literature methods (Petersen, 1950;Huisman, 1997;Have, 1997). A single crystal suitable for the X-ray diffraction study was obtained serendipitously in an attempt to synthesize a La III complex.…”

Section: S2 Experimentalmentioning

confidence: 99%

4-[4-(1H-Imidazol-4-yl)phenyl]-1H-imidazole

Wang¹,

Zhao²

2012

Acta Cryst E

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Synthesis ofN-(Dimethylsulfamoyl)aldimines, a New Type of Aldimine Derivative

Cited by 15 publications

References 14 publications

Highly CO₂ Selective Microporous Metal-Imidazolate Framework-Based Mixed Matrix Membranes

Highly CO₂ Selective Microporous Metal-Imidazolate Framework-Based Mixed Matrix Membranes

Synthesis of Enantiopure Benzyl Homoallylamines by Indium‐Mediated Barbier‐Type Allylation Combined with Enzymatic Kinetic Resolution: Towards the Chemoenzymatic Synthesis of N‐Containing Heterocycles

4-[4-(1H-Imidazol-4-yl)phenyl]-1H-imidazole

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Synthesis ofN-(Dimethylsulfamoyl)aldimines, a New Type of Aldimine Derivative

Cited by 15 publications

References 14 publications

Highly CO2 Selective Microporous Metal-Imidazolate Framework-Based Mixed Matrix Membranes

Highly CO2 Selective Microporous Metal-Imidazolate Framework-Based Mixed Matrix Membranes

Synthesis of Enantiopure Benzyl Homoallylamines by Indium‐Mediated Barbier‐Type Allylation Combined with Enzymatic Kinetic Resolution: Towards the Chemoenzymatic Synthesis of N‐Containing Heterocycles

4-[4-(1H-Imidazol-4-yl)phenyl]-1H-imidazole

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Highly CO₂ Selective Microporous Metal-Imidazolate Framework-Based Mixed Matrix Membranes

Highly CO₂ Selective Microporous Metal-Imidazolate Framework-Based Mixed Matrix Membranes