Synthesis of metal‐complexing latices via polymerization in microemulsion

Antonietti, Markus; Lohmann, Sabine; Eisenbach, Claus D.; Schubert, Ulrich S.

doi:10.1002/marc.1995.030160409

Cited by 30 publications

(24 citation statements)

References 17 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…Microemulsion polymerization yields stable latexes in the nanosize range (a 50 nm) that find applications in drug delivery, microencapsulation and biomedical diagnosis [156][157][158]. Most of these applications require highly functionalized particles, which have been prepared by using a second monomer bearing the desired functionality [159]. Larpent et al [160,161] reported on the use of polymerizable cosurfactants to produce highly functionalized nanoparticles.…”

Section: Microemulsion Polymerizationmentioning

confidence: 99%

Reactive surfactants in heterophase polymerization

Asúa¹,

Schoonbrood²

1998

Acta Polym.

134

View full text Add to dashboard Cite

Section: Microemulsion Polymerizationmentioning

confidence: 99%

Reactive surfactants in heterophase polymerization

Asúa¹,

Schoonbrood²

1998

Acta Polym.

134

View full text Add to dashboard Cite

“…Methacrylate-functionalized bipyridine ligands for the preparation of metal-complexing microlatex dispersions. [91] A system completely different to those shown above was presented by Lindsell et al in 1999, [92] in which they investigated polydiacetylenes with bipyridine ligands in the side chain as systems with nonlinear optical properties ( Figure 20). Figure 20.…”

Section: Polymers With Bipyridine Units In the Side Chainmentioning

confidence: 99%

Macromolecules Containing Bipyridine and Terpyridine Metal Complexes: Towards Metallosupramolecular Polymers

Schubert

Eschbaumer

2002

Angew. Chem. Int. Ed.

Self Cite

696

333

View full text Add to dashboard Cite

The ability of a broad range of N-heterocycles to act as very effective and stable complexation agents for several transition metal ions, such as cobalt(II), copper(II), nickel(II), and ruthenium(II), has long been known in analytical chemistry. This behavior was later utilized in supramolecular chemistry for the construction of highly sophisticated architectures, such as helicates, racks, and grids. The discovery of macromolecules by Staudinger in 1922 opened up avenues towards sophisticated materials with properties hitherto completely unknown. In the last few decades, the combination of macromolecular and supramolecular chemistry has been attempted by developing metal-complexing and metal-containing polymers for a wide variety of applications that range from filtration to catalysis. The stability of the polymer-metal complex is a fundamental requirement for such applications. In this respect, the use of bi- and terpyridines as chelating ligands is highly promising, since these molecules are known to form highly stable complexes with interesting physical properties with transition-metal ions. A large number of different structures have been designed for many different applications, but polymers based on the application of coordinative forces have been prepared in a few cases only. Furthermore, the synthetic procedures applied frequently resulted in low yields. During the last few years, strong efforts have been made in the direction of self-assembling and supramolecular polymers as novel materials with "intelligent" and tunable properties. In this review, an overview of this active area at the interface of supramolecular and macromolecular chemistry is given.

show abstract

“…W publikacjach [23][24][25][26] opisano wykorzystanie du-¿ej powierzchni w³aoeciwej nanolateksów do ich funkcjonalizowania odpowiednimi reagentami, np. kopolimerami styrenu, z nastêpuj¹cymi reaktywnymi komonomerami:…”

Section: Polimeryzacja I Kopolimeryzacjaunclassified

Microemulsions as the sources of nanolatexes and nanoreactors

Witek

Kochanowski²,

Pazdro³

et al. 2006

Polimery

View full text Add to dashboard Cite

Mikroemulsje jako Ÿród³o nanolateksów i nanoreaktorów Streszczenie-W artykule o charakterze przegl¹dowym przedstawiono zasady klasyfikacji emulsji, a tak¿e ogólnie scharakteryzowano mikroemulsje stanowi¹ce podstawowy przedmiot opracowania. Szczegó³owo omówiono kilka najwa¿niejszych kierunków praktycznego wykorzystania odwróconych mikroemulsji (typu w/o), mianowicie prowadzenie w takim oerodowisku procesów polimeryzacji i kopolimeryzacji, formowanie nanometrycznych cz¹stek nieorganicznych, syntezy bioorganiczne z wykorzystaniem enzymów, a tak¿e syntezy organiczne z udzia³em reagentów hydrofilowych i hydrofobowych. S³owa kluczowe: odwrócone mikroemulsje, nanolateksy, nanocz¹stki nieorganiczne, enzymatyczne syntezy bioorganiczne, kompatybilne rozpuszczalniki. MICROEMULSIONS AS THE SOURCES OF NANOLATEXES AND NANOREACTORS Summary-In the review the rules of emulsions' classification were presented. Microemulsions, being the subject of the work, were generally characterized (Fig. 1-5, Table 1). Some most important features of practical applications of reversed microemulsions (w/o type) were discussed in detail, namely processes of polymerization or copolymerization accomplished in such environment, formation of nanometric inorganic particles (Fig. 6), bioorganic syntheses using enzymes (Fig. 7) as well as the performance organic syntheses with hydrophilic and hydrophobic reagents.

show abstract

Synthesis of metal‐complexing latices via polymerization in microemulsion

Cited by 30 publications

References 17 publications

Reactive surfactants in heterophase polymerization

Reactive surfactants in heterophase polymerization

Macromolecules Containing Bipyridine and Terpyridine Metal Complexes: Towards Metallosupramolecular Polymers

Microemulsions as the sources of nanolatexes and nanoreactors

Contact Info

Product

Resources

About