Synthesis of Novel Covalently Linked Dimeric Phthalocyanines

Lyubimtsev, Alexey; Vagin, Sergei I.; Syrbu, Sergej; Hanack, Michael

doi:10.1002/ejoc.200600733

Cited by 24 publications

(14 citation statements)

References 19 publications

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“…4‐(3‐hydroxyphenoxy)benzene‐1,2‐dicarbonitrile ( 1 ) was synthesized as described in Ref. from resorcinol and 4‐nitrophthalonitrile. 1 was obtained as a yellowish powder with a yield of 80%.…”

Section: Methodsmentioning

confidence: 99%

Dual‐curing thermosetting monomer containing both propargyl ether and phthalonitrile groups

Bulgakov

Сулимов

Babkin

et al. 2017

J of Applied Polymer Sci

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Novel self-curing monomer containing two thermosetting groups, namely propargyl ether and phthalonitrile (PN) in a molecular structure, is synthesized and investigated. The study of catalyzed and uncatalyzed curing is performed and high heat release during curing is observed. This disadvantage can be adjusted by catalysis of propargyl ether polymerization with Ni (II), Co (II), and Cu (II) salts. The cured monomer possesses high thermal properties featured to phthalonitrile matrices (Heat deflection temperature, HDT 5 428 8C, T 5% 5 499 8C) and moderate mechanical properties (E 5 4.9 6 0.65 GPa, G IC 5 106 6 26 J/m 2 ), it can be applied as a high temperature matrix for carbon fiber reinforced plastics (CFRP). Low melt viscosity (223 mPa s at 120 8C) of the monomer provides a possibility to consider its application for composite material formation by vacuum infusion or resin transfer molding (RTM) techniques, which are exceptionally rarely applied for matrices with HDT > 300 8C but allow to obtain composites of complex shape with minimal joining parts.

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Section: Methodsmentioning

confidence: 99%

Dual‐curing thermosetting monomer containing both propargyl ether and phthalonitrile groups

Bulgakov

Сулимов

Babkin

et al. 2017

J of Applied Polymer Sci

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“…Monomers 1 and 2 [1] and resorcinol derivative 3 [8] were obtained according to the literature methods. Phenol was obtained from Sigma Aldrich and purified by vacuum sublimation.…”

Section: Experimental Design Materials and Methodsmentioning

confidence: 99%

Hydrolysis rate constants and activation parameters for phosphate- and phosphonate-bridged phthalonitrile monomers under acid, neutral and alkali conditions

et al. 2017

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Hydrolysis data for Bis(3-(3,4-dicyanophenoxy)phenyl) phenyl phosphate and Bis(3-(3,4-dicyanophenoxy)phenyl) phenylphosphonate under pH 4, 7 and 10 are presented. Conversion/time plots collected by HPLC analysis, typical chromatograms and NMR spectra of the reactions products are given. Pseudo-first order rate constants are determined for both substrates at 25, 50 and 80 °C. Activation parameters were calculated from Arrhenius equation.

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“…С помощью реакции алкилирования мезо-оксифенилпорфиринов был осуществлен синтез серии порфиринов с активными группами. [29,30] Обобщенная схема синтеза представлена на Схеме 8.…”

Section: порфирины Porphyrinsunclassified

Synthesis of Molecular Synthons for Porphyrinpolymers

Агеева¹,

Сырбу²,

Койфман³

2009

MHC

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Peculiarities of the unique structure of porphyrins, possibilities of their peripheral functionalization, ability of metal complexes to extracoordination allow to use them for inclusion in porphyrin-polymer systems in order to endow them with specific properties, determined by tetrapyrrole macrocyclic compounds and their complexes. Porphyrins and their analogues being immobilised on a polymer carrier not only preserve their useful properties, but even strengthen them due to cooperative interactions in polymer chains, separation of active centres, increase of stability of tetrapyrrole fragments This review systematise methods of synthesis of meso-phenyl substituted porphyrins which can be used for fastening on a polymer-carrier. The general approaches to functionalization of porphyrin monomers and their immobilization on synthetic polymers by macromolecular reactions and copolymerization are considered. Strategy of porphyrin-polymer syntheses is based on the previoiusly obtained regularities of mutual influence of the structure of tetrapyrrolic macroheterocycles and polymer-carriers and their ability to self-organization.

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Synthesis of Novel Covalently Linked Dimeric Phthalocyanines

Cited by 24 publications

References 19 publications

Dual‐curing thermosetting monomer containing both propargyl ether and phthalonitrile groups

Dual‐curing thermosetting monomer containing both propargyl ether and phthalonitrile groups

Hydrolysis rate constants and activation parameters for phosphate- and phosphonate-bridged phthalonitrile monomers under acid, neutral and alkali conditions

Synthesis of Molecular Synthons for Porphyrinpolymers

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