Synthesis of RbREF4 (RE=Pr, Nd, Sm, Eu, and Tb) and RbRE2F7 (Dy, Ho, Er and Yb) under non-aqueous conditions

Tripathi, Vikash Kumar; Saroj, Sanjay Kumar; Nagarajan, Rajamani

doi:10.1016/j.jfluchem.2015.03.001

Journal of Fluorine Chemistry

2015

DOI: 10.1016/j.jfluchem.2015.03.001

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Synthesis of RbREF4 (RE=Pr, Nd, Sm, Eu, and Tb) and RbRE2F7 (Dy, Ho, Er and Yb) under non-aqueous conditions

Vikash Kumar Tripathi

Sanjay Kumar Saroj

Rajamani Nagarajan

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Cited by 4 publications

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“…5b, bottom), which correspond to 3 H 4 -3 P 2 , 3 H 4 -3 P 1 , 1 I 6 , 3 H 4 -3 P 0 and 3 H 4 -1 D 2 of Pr 3+ , respectively. 26,36 For RBCs-SmCs, there are two visible intensities in the visible region at wavelengths of 407 nm and 472 nm (Fig. 5c, bottom), which correspond to 6 H 5/2 -6 P 3/2 and 6 H 5/2 -4 G 7/2 of Sm 3+ , respectively.…”

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Optically active multi-helical erythrocyte-like Ln(OH)CO₃ (Ln = La, Ce, Pr and Sm)

Chen

et al. 2016

Phys. Chem. Chem. Phys.

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Hierarchical erythrocyte-like Ln(OH)CO3 with nanosized chiral structure-induced circular dichroism responses were fabricated. The CD responses were observed not only in the UV region but also in the visible region, and are assigned to the electronic transitions from the valence band to the conduction band and the mixed coupling effect between the hierarchical left-handed-assembled Ln(OH)CO3 nanorods in the multi-helical RBC-like architecture.

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confidence: 99%

Optically active multi-helical erythrocyte-like Ln(OH)CO₃ (Ln = La, Ce, Pr and Sm)

Chen

et al. 2016

Phys. Chem. Chem. Phys.

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ChemInform Abstract: Synthesis of RbREF₄ (RE: Pr, Nd, Sm, Eu, and Tb) and RbRE₂F₇ (Dy, Ho, Er and Yb) under Non‐aqueous Conditions.

2015

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Synthesis of RbREF 4 (RE: Pr, Nd, Sm, Eu, and Tb) and RbRE2F7 (Dy, Ho, Er and Yb) under Non-aqueous Conditions. -Crystalline phases of the title compounds are prepared by the reaction of Ln(acac) 3 (Ln: lanthanide) with RbF in MeOH (25 C, 12 h). Compounds with the RbLnF4 stoichiometry are obtained only for Ln: Pr, Nd, Sm, Eu, and Tb (cubic space group Fm3m, powder XRD). The RbLn2F7 compounds (Ln: Dy, Ho, Er, Yb) crystallizes in the orthorhombic space group Pnma. Optical transitions arising from the f-shell of the rare earth ions are observed in the UV/Vis and photoluminescence spectra. -(TRIPATHI, V. K.; SAROJ, S. K.; NAGARAJAN*, R.; J. Fluorine Chem. 175 (2015) 22-27, http://dx.

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Perovskite (ACuF3) to double perovskite (A3CuF6) (A = K, Rb) transformation by a simple shaking procedure with hydrogen peroxide

Saroj

Singh

Nagarajan

2018

Solid State Sciences

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Synthesis of RbREF4 (RE=Pr, Nd, Sm, Eu, and Tb) and RbRE2F7 (Dy, Ho, Er and Yb) under non-aqueous conditions

Cited by 4 publications

References 18 publications

Optically active multi-helical erythrocyte-like Ln(OH)CO₃ (Ln = La, Ce, Pr and Sm)

Optically active multi-helical erythrocyte-like Ln(OH)CO₃ (Ln = La, Ce, Pr and Sm)

ChemInform Abstract: Synthesis of RbREF₄ (RE: Pr, Nd, Sm, Eu, and Tb) and RbRE₂F₇ (Dy, Ho, Er and Yb) under Non‐aqueous Conditions.

Perovskite (ACuF3) to double perovskite (A3CuF6) (A = K, Rb) transformation by a simple shaking procedure with hydrogen peroxide

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Synthesis of RbREF4 (RE=Pr, Nd, Sm, Eu, and Tb) and RbRE2F7 (Dy, Ho, Er and Yb) under non-aqueous conditions

Cited by 4 publications

References 18 publications

Optically active multi-helical erythrocyte-like Ln(OH)CO3 (Ln = La, Ce, Pr and Sm)

Optically active multi-helical erythrocyte-like Ln(OH)CO3 (Ln = La, Ce, Pr and Sm)

ChemInform Abstract: Synthesis of RbREF4 (RE: Pr, Nd, Sm, Eu, and Tb) and RbRE2F7 (Dy, Ho, Er and Yb) under Non‐aqueous Conditions.

Perovskite (ACuF3) to double perovskite (A3CuF6) (A = K, Rb) transformation by a simple shaking procedure with hydrogen peroxide

Contact Info

Product

Resources

About

Optically active multi-helical erythrocyte-like Ln(OH)CO₃ (Ln = La, Ce, Pr and Sm)

Optically active multi-helical erythrocyte-like Ln(OH)CO₃ (Ln = La, Ce, Pr and Sm)

ChemInform Abstract: Synthesis of RbREF₄ (RE: Pr, Nd, Sm, Eu, and Tb) and RbRE₂F₇ (Dy, Ho, Er and Yb) under Non‐aqueous Conditions.