Synthesis of Single-Crystal LiNi_0.7Co_0.15Mn_0.15O₂ Materials for Li-Ion Batteries by a Sol–Gel Method

Abstract

Single-crystal cathode with a submicron particle size exhibits better cyclic stability and safety than their polycrystalline counterparts. However, high-temperature sintering, tedious steps, and unexpected product greatly hinder its industrial applications. Herein, we proposed to prepare single-crystal LiNi 0.7 Co 0.15 Mn 0.15 O 2 by a sol−gel method, which can achieve uniform mixing at the molecular level. Besides, particle agglomeration almost does not occur for the products obtained at 890 °C, so the synthesis route does not require any crushing or molten-salt addition process. Single-crystal cathode particles have a diameter of about 1 μm. Compared with the conventional polycrystalline Li-Ni 0.7 Co 0.15 Mn 0.15 O 2 , the as-prepared single-crystal material exhibits improved thermal stability, less microcrack, and lower transitionmetal dissolution. As a result, the long-life performance is improved for both coin cells and Al-shell cells. KEYWORDS: single-crystal cathodes, sol−gel, LiNi 0.7 Co 0.15 Mn 0.15 O 2 , Al-shell full cell, microcrack, Ni-rich cathode

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