Synthesis of Vanadyl Complexes of N-Confused Porphyrins and Their <i>Bromoperoxidase</i>-like Catalytic Activity

Kumar, Rajesh; Prakash, Ved; Sankar, Muniappan

doi:10.1021/acs.inorgchem.4c01222

Inorg. Chem.

2024

DOI: 10.1021/acs.inorgchem.4c01222

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Synthesis of Vanadyl Complexes of N-Confused Porphyrins and Their Bromoperoxidase-like Catalytic Activity

Rajesh Kumar,

Ved Prakash,

Muniappan Sankar

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2024

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Cited by 2 publications

References 60 publications

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Utilization of Tin(IV) Complex of N‐Confused Porphyrin for Antiproliferative Activity and Antimicrobial Photodynamic Chemotherapy

Kumar,

Kumar Chaudhary,

Prasad

et al. 2024

Chemistry An Asian Journal

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Sn(IV) complex of N‐Confused Porphyrin (Sn(IV)‐NCP) has been prepared and characterized by several spectroscopic techniques to verify its structure and purity. Sn(IV)‐NCP shows a red shift in both the Soret and Q bands compared to the free base NCTPP. The last Q band appears in the NIR region. Based on these characteristics, we investigated the antiproliferative properties and antimicrobial photodynamic therapy (a‐PDT) efficiency of Sn(IV)‐NCP against the bacteria Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). Further, we investigated the photodynamic activity of Sn (IV)‐NCP against Michigan cancer foundation‐7 (MCF‐7) cancer cells, to assess its potential as an effective therapeutic agent. Treated MCF‐7 cells with the compound show cytotoxic effects as compared to the untreated ones. At a higher concentration (128 µg/ml), Sn(IV)‐NCP exhibited 90% inhibition, while at a lower concentration (32 µg/ml), it showed 70% inhibition in MCF‐7 cells. The IC50 value for this compound against MCF‐7 cells was found 16.67 µg/ml. At 32 µg/ml, Sn(IV)‐NCP showed only around 4% cell inhibition, indicating minimal cytotoxic effects on human embryonic kidney cells (HEK293).

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Utilization of Tin(IV) Complex of N‐Confused Porphyrin for Antiproliferative Activity and Antimicrobial Photodynamic Chemotherapy

Kumar,

Kumar Chaudhary,

Prasad

et al. 2024

Chemistry An Asian Journal

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Vanadyl Salen Complex Anchored on Polymer: An Efficient Catalyst for Selective Oxidation of Sulfides to Sulfoxides

Foumani,

Khorshidi,

Shojaei

2024

J Inorg Organomet Polym

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Synthesis of Vanadyl Complexes of N-Confused Porphyrins and Their Bromoperoxidase-like Catalytic Activity

Cited by 2 publications

References 60 publications

Utilization of Tin(IV) Complex of N‐Confused Porphyrin for Antiproliferative Activity and Antimicrobial Photodynamic Chemotherapy

Utilization of Tin(IV) Complex of N‐Confused Porphyrin for Antiproliferative Activity and Antimicrobial Photodynamic Chemotherapy

Vanadyl Salen Complex Anchored on Polymer: An Efficient Catalyst for Selective Oxidation of Sulfides to Sulfoxides

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