Synthesis, spectroscopic and electronic characterizations of two half sandwich ruthenium(II) complexes with 2-(2′-hydroxyphenyl)-benzoxazole and 4-picolinic acid ligands

Reactivity of 2-(2-hydroxyphenyl)benzoxazole and 2-(2-hydroxyphenyl)benzothiazole towards group 10 transition metals. Evaluation in palladium catalyzed Suzuki–Miyaura C–C couplings

“…Being known now a days complexes of almost any transition metal [4][5][6][7][8][9][10][11][12][13] and rare earth [14][15][16][17]. Thus, metal derivatives of HPBO and HPBT have attracted much attention due to their optical and luminescent properties.…”

Half-sandwich ruthenium(II) complexes with N- and N,(N,O)-donor ligands: molecular, electronic structures, and computational study

“…p ligand * transition are observed. The complicated structure of the luminescence spectra suggest that more than one state is involved in luminescence processes [20].…”

“…Thus, the studies of electronic structures of complexes are an important area of chemistry. The basic researches reported in this article combine interest in ruthenium complexes and half-sandwich coordination compounds with N(O)-donors [18][19][20][21][22][23].…”

Spectral, structural and DFT studies of platinum group metal 3,6-bis(2-pyridyl)-4-phenylpyridazine complexes and their ligand bonding modes

“…From Table S3 of Supplementary material we can see that the positions of binding have discernible effects on the stability and geometrical structure of the complexes. Comparing the computed results of the parent complexes 2, 3, 4, 5, 6 with the experimental data (see Table 1), we find that the computed coordination bond lengths (Ru-N) are shorter than the corresponding experimental value by 1-3%, the largest differences being found for the metal-arene carbon distances [50]. Computed coordinated bond angles are wider by 2% than those found experimentally.…”