Synthesis, spectroscopic characterization, and magnetic properties of unusual 3,5-dialkyl-1,2,4-triazole compounds containing N-bridging isothiocyanato ligands. X-ray structure of trinuclear bis[(.mu.-thiocyanato-N)bis(.mu.-3,5-diethyl-1,2,4-triazole-N1,N2)bis(thiocyanato-N)(3,5-diethyl-1,2,4-triazole-N1)nickel(II)-N,N1,N1']nickel(II) dihydrate

Abstract

Die Reaktion der Mn‐, Co‐ und Ni‐nitrate in Wasser mit NH4NCS und den Liganden liefert die Komplexe (l).

One-dimensional ladder like and two-dimensional polymorphs of heterometallic thiocyanate bridged copper(II) and mercury(II) coordination polymer: Syntheses, structural, vibration, luminescence and EPR studies

“…S4 and S5 in supplementary material, respectively. The IR spectrum of 1 exhibits a strong peak at 2172 cm À1 and also very strong absorption bands at 2132, 2122 and 2105 cm À1 which are in agreement with the generally employed criterion that m(C"N) P 2100 cm À1 indicates a thiocyanate bridge with a 1,3-l or 1,1,3-l bridging mode [54][55][56]. Compared to the 1, compound 2 also exhibits the same bands (2171, 2123, 2104 cm À1 ) except the band at 2132 cm À1 .…”

Coordinative Versatility of Guanazole [3,5‐Diamino‐1,2,4‐triazole]: Synthesis, Crystal Structure, EPR, and Magnetic Properties of a Dinuclear and a Linear Trinuclear Copper(II) Complex Containing Small Bridges and Triazole Ligands

“…Several linear trinuclear coordination compounds of this type, i.e. containing two 1,2,4-triazole ligands bridging through N1,N2 atoms and either a halogen anion or a second small bridging anion, have been previously reported: (a) three Co II compounds with F - [28,29] or N-bridging NCS -ligands, [30] (b) three Ni II -N(NCS -) compounds, [30][31][32] (c) one Mn(II,III,II) complex with hydroxido bridges, [33] (d) two Cd II compounds containing Cl - [20] or N,N-isothiocyanato bridges, [20] and (e) a few Cu II compounds (Table 3). The first structurally characterized (triazole)copper(II) compound to include µ-chloride ions was [{Cu(Htrz)Cl 2 } ϱ ], but it consists of an infinite chain with two Cl -and a single triazole ligand per pair of copper atoms instead of one Cl -and two triazole ligands.…”

Syntheses, crystal structures and luminescent properties of copper(I)-halide complexes constructed by 4-amino-3,5-dimethyl-1,2,4-triazole

“…The ligand admtz was synthesized according to the literature method [9]. Other chemicals were obtained from commercial sources and used without further purification.…”