Synthesis, vibrational and quantum chemical investigations of hydrogen bonded complex betaine dihydrogen selenite

Arjunan, V.; Marchewka, M.K.; Kalaivani, M.

doi:10.1016/j.saa.2012.07.054

Cited by 19 publications

(5 citation statements)

References 55 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…From the graph, it is understood that 4-ASZC possesses a positive temperature coefficient. It is concluded that the magnitude of water solubility is slightly higher compared with that of dimethyl formide due to N-O-H bond break in high temperature and the formation of ionic bond [36,37].…”

Section: Solubilitymentioning

confidence: 95%

“…The crystal structure is established by the intramolecular hydrogen bond to form a threedimensional network. The whole system of crystal is neutral due to the crystal system in zwitter ionic nature [36]. Hence it is concluded that the formation of N-H-O type of hydrogen bond interaction is the most possible one.…”

Section: Single Crystal Analysismentioning

confidence: 99%

“…The crystal parameters are listed in Table 1. The grown 4-ASZC crystal consists of nitrogen (N), hydrogen (H) and oxygen (O) which make a new hydrogen bond like N-H-O [34,36]. Similarly, zinc metal ion (Zn 2+ ) formed a new coordinate bond with oxygen (O) like a bidentate ligand (Zn 2+ -O-S) [37].…”

Section: Growth Of 4-aszc Crystal Based On Zinc Metal With Saamentioning

confidence: 99%

“…Sulphanilic acid (SAA) compound is widely used in the field of radiation therapy, biological, biomedical, supercapacitor and drug delivery application [14][15][16]. It is also used as a monomer for the preparation of various copolymers and shows a conductivity, bio-imaging, humidity sensor application [15,36,37]. The sulfanilate anion can act as a hydrogen bond donor and acceptor due to its aminogroup and protonated sulphonate moiety [21].…”

Section: Introductionmentioning

confidence: 99%

See 3 more Smart Citations

Growth and Characterization of Semiorganic Non-linear Optical Material: (((4-aminophenyl)sulphonyl)oxy)zinc(II)chloride Crystal

Vinoth¹,

Vetrivel²,

Gopinath³

et al. 2019

Journal of Taibah University for Science

View full text Add to dashboard Cite

Growth and characterization of nonlinear optical (NLO) crystal of (((4-aminophenyl)sulphonyl) oxy)zinc(II)chloride (4-ASZC), based on zinc chloride with sulphanilic acid by the slow evaporation method has been studied and reported in this paper. The single crystal X-ray diffraction study confirmed the monoclinic system with centrometric space group P2 1 . The sharp Bragg's peak in powder X-ray diffraction analysis identifies the crystalline nature. Optical properties, such as low cut-off wavelength (251 nm), optical band gap (E g = 4.40 eV), reflectance (R), extinction coefficient (K) and refractive index (n), are calculated from the UV-vis-NIR spectrum. The presence of functional groups are confirmed by the FT-IR spectroscopy. The placement of protons and carbons was determined by the NMR technique. The photoluminescence study shows the green light emission. The grown crystal is thermally stable up to184°C. The NLO efficiency is 0.5 times greater than that of standard KDP. The mechanical properties were analysed. The dielectric constant (ε), dielectric loss (ε ), imaginary dielectric constant (ε ), AC conductivity (σ ac ) and Cole-Cole graphs were plotted. The surface morphology and the particle size of the crystal were determined by the FESEM technique. ARTICLE HISTORY

show abstract

Section: Solubilitymentioning

confidence: 95%

Section: Single Crystal Analysismentioning

confidence: 99%

Section: Growth Of 4-aszc Crystal Based On Zinc Metal With Saamentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Growth and Characterization of Semiorganic Non-linear Optical Material: (((4-aminophenyl)sulphonyl)oxy)zinc(II)chloride Crystal

Vinoth¹,

Vetrivel²,

Gopinath³

et al. 2019

Journal of Taibah University for Science

View full text Add to dashboard Cite

show abstract

“…Hybrid organic-inorganic materials with distinctive properties have a great importance from combining both organic and inorganic components into the material [1][2][3][4]. They are characterized by a large variety of structures framework dimensionality build from chains, layers, or three-dimensional connections [5,6] as well as a correlation between the structural features and a vast diversity of physical properties from their potential applications such as magnetic, optical, luminescence and electric [7][8][9][10][11]. Hybrid halogen-based materials have demonstrated exciting properties from the renewal of zero-dimensional structures belonging to alums and Tutton's salts [12][13][14][15].…”

Section: Introductionmentioning

confidence: 99%

Growth, crystal structure, Hirshfeld surface and vibrational properties of a new supramolecular hybrid material: (C4H7N2)2TeBr6

et al. 2022

View full text Add to dashboard Cite

A novel tellurium (IV) hybrid compound with 2-methylimidazole was prepared. The crystal was grown by slow evaporation method from aqueous solutions at room temperature giving birth to a new compound with formula (C4H7N2)2TeBr6. The structure was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic system, space group C 2/c, with the following parameters: a = 18.577(2)Å, b = 9.1497(10)Å, c = 13.5355(17)Å, α = 90°, β = 123.835(5)°, γ = 90° and Z = 8. The structure was solved with a final R = 0.044 for 2783 independent reflections. The crystal arrangement consists of [TeBr6]2− anions surrounded by [C4H7N2]2+ cations. The stability of the structure was ensured by hydrogen bonding contacts (N–H…Br) lengths that are in the range of 3.490–3.682 Å. The infrared spectra (FTIR) were recorded in the 4000–550 cm−1, confirming the existence of vibrational modes that correspond to the organic and inorganic groups. The crystal packing was stabilized mainly by Br…H (73.6%) interactions. Hirshfeld surface calculations were conducted to further investigate intermolecular interactions, associated 2D fingerprint plots and enrichment ratio, revealing the quantitatively relative contribution of these interactions in the crystal packing.

show abstract

Reactions of Amino Acids with Acids

Fleck

Petrosyan

2014

Salts of Amino Acids

View full text Add to dashboard Cite

Synthesis, vibrational and quantum chemical investigations of hydrogen bonded complex betaine dihydrogen selenite

Cited by 19 publications

References 55 publications

Growth and Characterization of Semiorganic Non-linear Optical Material: (((4-aminophenyl)sulphonyl)oxy)zinc(II)chloride Crystal

Growth and Characterization of Semiorganic Non-linear Optical Material: (((4-aminophenyl)sulphonyl)oxy)zinc(II)chloride Crystal

Growth, crystal structure, Hirshfeld surface and vibrational properties of a new supramolecular hybrid material: (C4H7N2)2TeBr6

Reactions of Amino Acids with Acids

Contact Info

Product

Resources

About