Synthesisi and Structure of a new Polynuclear Silver Complex [Ag&lt;SUB&gt;4&lt;/SUB&gt;(dppe)&lt;SUB&gt;3&lt;/SUB&gt;(NO&lt;SUB&gt;3&lt;/SUB&gt;)&lt;SUB&gt;4&lt;/SUB&gt;]

In the title chain compound, [Ag(NO3)(C26H24P2)]n, the bis(diphenylphosphino)ethane (dppe) units link the Ag+ ions into chains along [001]. A nitrate anion is coordinated to the Ag atom. There is a centre of symmetry at the mid-point of the ethane C—C bond and a twofold rotation axis passes through the Ag, N and terminal O atoms. Each Ag atom is four-coordinated in a distorted tetrahedral geometry by two O atoms of the nitrate anion and two P atoms of dppe ligands. The two aromatic rings are oriented at a dihedral angle of 73.77 (3)°.

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Synthesisi and Structure of a new Polynuclear Silver Complex [Ag<SUB>4</SUB>(dppe)<SUB>3</SUB>(NO<SUB>3</SUB>)<SUB>4</SUB>]

Cited by 4 publications

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catena-Poly[[(nitrato-κ²O,O′)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ²P:P′]

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Synthesisi and Structure of a new Polynuclear Silver Complex [Ag<SUB>4</SUB>(dppe)<SUB>3</SUB>(NO<SUB>3</SUB>)<SUB>4</SUB>]

Cited by 4 publications

References 0 publications

Synthesis of the first polymeric Cu(I) dppe (dppe=1,2-bis(diphenylphosphino)ethane) complexes

Synthesis of the first polymeric Cu(I) dppe (dppe=1,2-bis(diphenylphosphino)ethane) complexes

Polynuclear silver(I) complexes of triphenylphosphine and 2-aminopyrimidine: Synthesis, structural characterization and spectroscopic properties

catena-Poly[[(nitrato-κ2O,O′)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ2P:P′]

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catena-Poly[[(nitrato-κ²O,O′)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ²P:P′]