In this paper, we present a new program synthesis algorithm based on reinforcement learning. Given an initial policy (i.e. statistical model) trained off-line, our method uses this policy to guide its search and gradually improves it by leveraging feedback obtained from a deductive reasoning engine. Specifically, we formulate program synthesis as a reinforcement learning problem and propose a new variant of the policy gradient algorithm that can incorporate feedback from a deduction engine into the underlying statistical model. The benefit of this approach is twofold: First, it combines the power of deductive and statistical reasoning in a unified framework. Second, it leverages deduction not only to prune the search space but also to guide search. We have implemented the proposed approach in a tool called Concord and experimentally evaluate it on synthesis tasks studied in prior work. Our comparison against several baselines and two existing synthesis tools shows the advantages of our proposed approach. In particular, Concord solves 15% more benchmarks compared to Neo, a state-of-the-art synthesis tool, while improving synthesis time by 8.71× on benchmarks that can be solved by both tools.