Synthetic and Spectroscopic Studies on Some Bis(dialkyldithiocarbomato)-arsenic(III) O,O'-dialkyldithiophosphates

Synthetic, spectroscopic and antimicrobial studies of bis(dialkyldithiocarbamato)diorganodithiophosphatobismuth(III) complexes

“…(10) In addition, these derivatives also exhibit the expected signals due to resonances of the corresponding ethyl, npropyl, i-propyl, n-butyl, i-butyl and phenyl protons of diorganodithiophosphate moieties and are comparable with the earlier reported data. 30 -34 The coupling of OCH 2 protons (attached to the carbon atom nearest to the phosphorus atom) with 31 P nuclei is also observed in compound numbers 1,2,4,5,7,8,10 and 11 (Table 4).…”

Synthetic, spectral, thermal and antimicrobial studies of bis(N,N‐dialkyldithiocarbamato)arsenic(III) and antimony(III) complexes with diphenyldithiophos‐phate and diphenyldithiophosphinate

“…19 In addition, these ligand complexes have important applications in the production of petroleum derivatives, lubricants and polymers, where they are used as accelerators of vulcanization, antioxidants and antihumidity. 20,21 In continuation of our recent interest on studies on main group metals with sulfur donor organic ligands, 22,23 we report iodometrically 29 and sulfur was estimated gravimetrically as barium sulfate. 29,30 Molecular weights were determined cryoscopically in benzene.…”

“…This shifting indicates most probably anisobidentate chelation of thiophosphoryl sulfur to metal atom. The bands of weak to medium intensities present in the region 530-545, 330-340 and 310-320 cm −1 are assigned due to (P-S), (As-S) and (Sb-S) stretching vibrations, 22,23,29 respectively. The (P-S) stretching bands are present in all the complexes at 530-545 cm −1 , the corresponding (As-S) and (Sb-S) stretching bands are present in their respective complexes.…”

“…11,22,23,33 -36 The dimethyldithiocarbamate derivatives exhibited a singlet at 3.38-3.42 ppm due to methyl protons while diethyldithiocarbamate derivatives exhibited a triplet at 1.24-1.31 ppm and a quartet at 3.73-3.82 ppm due to CH 3 and -NCH 2 proton resonances, respectively, and pyrrolidinedithiocarbamate derivatives exhibited two complex patterns at 2.01-2.12 and 3.72-3.78 ppm due to -CH 2 -CH 2 -and -NCH 2 protons, respectively. 22,23 These complexes showed multiplet signals at 7.11-8.05 ppm due to the phenyl ring protons.…”

Alkoxo-Bridged Heterobinuclear Derivatives of Arsenic(III) and Boron Based on Dithiophosphate Ligands: Synthesis and Characterization

“…Although during the last two decades there has been significant development in the chemistry of heterobimetallic alkoxides of heavier group 15 elements, 1-17 except for two examples, 18 there is a dearth of analogous studies concerning arsenic(III), though homodinuclear derivatives 19 of arsenic(III) containing deprotonated dithiophosphates and an isopropoxoarsenate group as well as mixed ligand dialkyldithiophosphate derivatives of arsenic(III) have already been reported earlier [20][21][22] in the literature. In view of the previous statement, we report the synthesis and characterization of heterobinuclear alkoxide derivatives of arsenic(III) with boron.…”