Systematic studies of hydroxyapatite/terpene hybrid microspheres: natural rosin-based phosphorus sources and chemical structures of coordination compounds

Yang, Mingsheng; Xu, Pengfei; Zhao, Xingyu; Tian, Chao; Han, Chunrui; Song, Jié

doi:10.1088/2053-1591/ab208f

Cited by 3 publications

(4 citation statements)

References 21 publications

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“…The phosphorus in hybrid materials may be produced by the hydrolysis of rosin phosphate ester. While it should be noted that the absorption peaks of carbonyl group shift from 1640 cm −1 to 1625 cm −1 in figures 2(E) and (F), which may be caused by the formation of coordination compound between calcium ion and carbonyl group [36].…”

Section: Ft-irmentioning

confidence: 89%

“…However, under alkaline conditions, due to the hydroxyl force on the surface of the sample, the particles gather to form irregular blocks (a4) [37]. The difference of morphology may be due to the different charge action of the system under different pH conditions, after hydrolysis of RAPM, it forms different complexes with Ca 2+ controls the specific growth of materials [36].…”

Section: Sem 321 Sem Of Rosin@ap Materials By Hydrothermal Methodsmentioning

confidence: 99%

“…But in alkaline condition RAPD@AP the self-assembly ability is weak, and it is composed of accumulated particles. The difference between RAPM@AP and RAPD@AP may be due to that there are two phosphoester groups in RAPD, and the hydrolysis degree is different from that of RAPM under the same conditions [36].…”

Section: Sem 321 Sem Of Rosin@ap Materials By Hydrothermal Methodsmentioning

confidence: 99%

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Preparation and application of rosin@apatite hybrid material with new natural surfactants based on in-situ reaction by sol-gel method

Wang,

Guo,

Yang

et al. 2024

Mater. Res. Express

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Due to the combination of organic and inorganic advantages, organic@inorganic hybrid materials have important applications in drug-loading, water-treatment and other fields. Rosin@apatite (AP) hybrid materials with various morphologies were designed and obtained by in-situ reaction using two novel rosin-based phosphoester surfactants as organic phosphorus sources. The hybrid materials combined multi-ring, multi-electron groups of natural rosin diterpene and strong physical adsorption properties of apatite. Block and sheet rosin@AP hybrid materials were prepared by sol-gel method with mild reaction conditions. The materials have excellent adsorption capacity of phenol (9.2 mg/g) and loading capacity (492 mg/g) of adriamycin (DOX) induced by π–π stacking interaction with rosin bases. The content of rosin based organic materials in hybrid materials is as high as 47.5% by thermogravimetric analysis. The formation mechanism of hybrid materials was speculated in detail.

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Section: Ft-irmentioning

confidence: 89%

Section: Sem 321 Sem Of Rosin@ap Materials By Hydrothermal Methodsmentioning

confidence: 99%

Section: Sem 321 Sem Of Rosin@ap Materials By Hydrothermal Methodsmentioning

confidence: 99%

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Preparation and application of rosin@apatite hybrid material with new natural surfactants based on in-situ reaction by sol-gel method

Wang,

Guo,

Yang

et al. 2024

Mater. Res. Express

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“…This is due to multiple variables, such as the type, volume ratio, and concentration of the starting materials, as well as the reaction conditions, such as temperature and pressure [ 33 ]. Furthermore, the use of organic solvents can also pose some challenges, such as the need for appropriate safety precautions and the potential for toxicity [ 34 ]. Despite these challenges, the solvothermal method remains an important technique for the synthesis of CaP nanoparticles with tailored properties and functionality for bone tissue engineering and other applications.…”

Section: Synthesis Strategies For Calcium Phosphate-based Nanomaterialsmentioning

confidence: 99%

Calcium Phosphate-Based Nanomaterials: Preparation, Multifunction, and Application for Bone Tissue Engineering

Chen

et al. 2023

Molecules

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Calcium phosphate is the main inorganic component of bone. Calcium phosphate-based biomaterials have demonstrated great potential in bone tissue engineering due to their superior biocompatibility, pH-responsive degradability, excellent osteoinductivity, and similar components to bone. Calcium phosphate nanomaterials have gained more and more attention for their enhanced bioactivity and better integration with host tissues. Additionally, they can also be easily functionalized with metal ions, bioactive molecules/proteins, as well as therapeutic drugs; thus, calcium phosphate-based biomaterials have been widely used in many other fields, such as drug delivery, cancer therapy, and as nanoprobes in bioimaging. Thus, the preparation methods of calcium phosphate nanomaterials were systematically reviewed, and the multifunction strategies of calcium phosphate-based biomaterials have also been comprehensively summarized. Finally, the applications and perspectives of functionalized calcium phosphate biomaterials in bone tissue engineering, including bone defect repair, bone regeneration, and drug delivery, were illustrated and discussed by presenting typical examples.

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Preparation and drug-delivery study of functionalized hydroxyapatite based on natural polysaccharide gums with excellent drug-loading properties

Tian

Jiang

et al. 2020

Journal of Dispersion Science and Technology

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Systematic studies of hydroxyapatite/terpene hybrid microspheres: natural rosin-based phosphorus sources and chemical structures of coordination compounds

Cited by 3 publications

References 21 publications

Preparation and application of rosin@apatite hybrid material with new natural surfactants based on in-situ reaction by sol-gel method

Preparation and application of rosin@apatite hybrid material with new natural surfactants based on in-situ reaction by sol-gel method

Calcium Phosphate-Based Nanomaterials: Preparation, Multifunction, and Application for Bone Tissue Engineering

Preparation and drug-delivery study of functionalized hydroxyapatite based on natural polysaccharide gums with excellent drug-loading properties

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