2009
DOI: 10.1039/b900288j
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Systems chemistry and Parrondo’s paradox: computational models of thermal cycling

Abstract: A mathematical concept known as Parrondo's paradox motivated the development of several novel computational models of chemical systems in which thermal cycling was explored. In these kinetics systems we compared the rates of formation of product under cycling temperature and steady-sate conditions. We found that a greater concentration of product was predicted under oscillating temperature conditions. Our computational models of thermal cycling suggest new applications in chemical and chemical engineering syst… Show more

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Cited by 36 publications
(27 citation statements)
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“…For example, if (ρ, φ) = (1/3, 1/2) (and ε = 0), our results show that there is a globally asymptotically stable equilibrium with game B eventually played forever. This is contrary to a computational result of Dinís and Parrondo [11], who found the pattern [1,40] in this case (i.e., AB 40 AB 40 AB 40 · · · ). The anomaly is likely attributable to roundoff error; 64-bit arithmetic (C++) is insufficient here.…”
Section: Introductioncontrasting
confidence: 99%
“…For example, if (ρ, φ) = (1/3, 1/2) (and ε = 0), our results show that there is a globally asymptotically stable equilibrium with game B eventually played forever. This is contrary to a computational result of Dinís and Parrondo [11], who found the pattern [1,40] in this case (i.e., AB 40 AB 40 AB 40 · · · ). The anomaly is likely attributable to roundoff error; 64-bit arithmetic (C++) is insufficient here.…”
Section: Introductioncontrasting
confidence: 99%
“…The games have also received attention in many other fields [7], ranging from Brownian ratchets [8,9], nonlinear dynamics [10][11][12][13], biology [14,15], chemistry [16], and economics [17]. Different variants of the original Parrondo's games have been developed, including historydependent Parrondo's game [18], Parrondo's game with self-transition [4] and multi-player version of Parrondo's game [19][20][21].…”
Section: Introductionmentioning
confidence: 99%
“…Increasing our understanding of how to control decoherence is one of the motivating factors behind these developments in quantum game theory. It has been shown [77] that Parrondo's original games can be rather elegantly described in terms Onsager rate equations [78,79] -indeed the possibility of Parrondo-like effects in chemical kinetics has been explored in a computational chemistry setting [80]. Parrondo effects have also inspired work in the study of negative mobility phenomena [81], reliability theory [82], noise induced synchronization [83], spatial patterns via switching [84], and in controlling chaos [85,86].…”
Section: Developments In Parrondo's Paradox and Related Phenomenamentioning
confidence: 99%