2022
DOI: 10.1021/acs.inorgchem.1c03219
|View full text |Cite
|
Sign up to set email alerts
|

Tailoring Thermal Expansion of (LiFe)0.5xCu2–xP2O7 via Codoping LiFe Diatoms in Cu2P2O7 Oxide

Abstract: Tailoring the thermal expansion coefficient of negative thermal expansion (NTE) materials to achieve near-zero thermal expansion has attracted great attention recently. Here, LiFe diatoms are adopted to substitute Cu in Cu 2 P 2 O 7 oxide to design Li−O−P and Fe−O−P linkages, with the stronger bond strength of Li−O and Fe−O compared to Cu−O and hence lowering the bond strength of P−O. With increasing the diatomic LiFe in (LiFe) 0.5x Cu 2−x P 2 O 7 , new Raman bands corresponding to LiFeP 2 O 7 appear and the N… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Year Published

2022
2022
2024
2024

Publication Types

Select...
5

Relationship

0
5

Authors

Journals

citations
Cited by 5 publications
references
References 25 publications
0
0
0
Order By: Relevance