The development of contemporary college English teaching methods and practice should respect the subjective will of college students; fully tap their wisdom and potential; constantly innovate college English teaching methods, teaching practice activities, classroom teaching, and teaching evaluation models; create a good teaching atmosphere; and establish the concept of developmental evaluation. Through the innovation of teaching methods, college students’ actual language communication ability is cultivated, the teaching objectives and teaching methods of college English reading are innovated, and interactive, body language, role play, situational teaching, communicative teaching, and other teaching methods are used. The College English teaching quality evaluation is a classical multiple attribute decision making (MADM). In this article, the triangular Pythagorean fuzzy sets (TPFSs) are introduced, and the MADM problem is investigated under TPFSs. Based on the traditional dual generalized weighted Bonferroni mean operator and power average operator, the triangular Pythagorean fuzzy dual generalized power Bonferroni mean (TPFDGPBM) operator is proposed. Accordingly, the TPFDGPBM operator is employed to construct the triangular Pythagorean fuzzy MADM method. Finally, a numerical example for College English teaching quality evaluation is constructed to verify the TPFDGPBM technique.