Technologische Bedingungen zur Herstellung von Fettalkoholen durch katalytische Hochdruck‐Hydrierung

Haidegger, E.; Hodossy, L.

doi:10.1002/lipi.19620640406

Cited by 7 publications

(4 citation statements)

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“…Presumably, it should be possible and perhaps even desirable to produce only alcohols from these fatty acids. Certainly the highpressure hydrogenolysis of other oils and acids has been well studied (Haidegger and Hodossy, 1962;Pantula and Achaya, 1964;Klonowski et al, 1970). Production of alcohols rather than wax esters would be more expensive because of the higher pressures involved.…”

Section: Discussionmentioning

confidence: 99%

Synthetic Wax Esters and Diesters from Crambe and Limnanthes Seed Oils

Nieschlag¹,

Spencer²,

Madrigal³

et al. 1977

Product R&D

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His work involves chemical modifications of new crop seed oils in order to discover and develop new products of industrial utility. He received his bachelor's degree from Northwestern University and his master's degree from Bradley University. Prior to joining the Northern Center, he was employed by Commercial Solvents Corporation.Gayland F. Spencer graduated from Bradley University, Peoria, Illinois, in 1969 and has been engaged in the analysis and identification of lipid constituents. Richard V, Madrigal has been with the Agricultural Research Service for 18 years. Previously he was with the Glidden Company for 4 years. He holds a bachelor's degree from DePaul University. At the present time, he is engaged in characterization of unusual components in plant seed oils. J. A. Rothfus leads Horticultural and Special Crops Evaluation Research at the Northern Regional ResearchCenter investigating all aspects of plant resources utilization. Educated at Drake University and the University of Illinois, Dr. Rothfus has been involved in biochemical and natural products research for over 15 years.

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Section: Discussionmentioning

confidence: 99%

Synthetic Wax Esters and Diesters from Crambe and Limnanthes Seed Oils

Nieschlag¹,

Spencer²,

Madrigal³

et al. 1977

Product R&D

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“…The disadvantage is the high excess of methanol and rather high temperatures and pressures (200 a Activity is given in conversion of glycerides (c) or yield in alkyl (methyl) esters (y). Beyond this, hydrogenolysis takes place during direct hydrogenation of triglycerides to fatty alcohols and C 3 -diols and propanol [46,49,50]. However, still there is a need to develop a solid catalyst system which would allow the energy consumption in the conversion of oil to alkyl esters and glycerol to be reduced.…”

Section: Mixed Oxidesmentioning

confidence: 99%

“…The hydrogenolysis of FAME to fatty alcohols is typically conducted at pressures between 20 and 30 MPa [46,57,58], although high conversion rates can also be attained at a lower operating pressure level of about 14.0 MPa [47,62]. The hydrogenolysis of FAME to fatty alcohols is typically conducted at pressures between 20 and 30 MPa [46,57,58], although high conversion rates can also be attained at a lower operating pressure level of about 14.0 MPa [47,62].…”

Section: B Hydrogenation Of Fatty Esters To Saturated Fatty Alcoholsmentioning

confidence: 99%

Heterogeneous Catalysis in Oleochemistry

Gutsche

Rössler

Würkert³

2008

Handbook of Heterogeneous Catalysis

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“…2ARS, USDA. 451 otherwise be expected to undergo hydrogenolysis to either 1,2-propanediol or isopropyl alcohol (3,5,6) or both and to their corresponding esters.…”

Section: Introductionmentioning

confidence: 99%

Secondary products from high pressure hydrogenation of crambe oil

Spencer

Nieschlag

Rothfus

1974

J Americ Oil Chem Soc

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Hydrogenation of crambe oil, mainly an cga'dierucoyl triglyceride, in the presence of cadmium promoted copper-chromite provides long chain waxes being sought as sperm whale oil replacements. Gas liquid chromatography and gas chromatography-mass spectrometry analyses of secondary products indicate, however, that reduction proceeds rather differently from Adkins-type hydrogenations of triglycerides over copper-chromium oxide catalysts. Monoand diunsaturated alkenes ranging from C16-C2 4, odd chain lengths included, constitute ca. 1% of the product. Esters of crambe acids with methyl, ethyl, n-propyl, and isopropyl alcohols account for less than 5%. These alcohols and traces of 1,2-propanediol from the hydrogenolysis of glycerol occur in either the head gas or the reaction mixture or both. In contrast to published results for Adkins-type hydrogenations of triglycerides, n-propyl alcohol is far more abundant than isopropyl alcohol or 1,2-propanediol. Isopropyl esters of C-18 acids are not present, and those of C-22 acids constitute no more than 2% of the total esters. Low proportion of isopropyl esters and enrichment of C-22 acids in the secondary products compared with C-18 acids suggest that the acyl substituent at the/~-position of glycerol is eliminated during hydrogenation of crambe oil with a Cd-Cu-Cr catalyst.

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Technologische Bedingungen zur Herstellung von Fettalkoholen durch katalytische Hochdruck‐Hydrierung

Cited by 7 publications

References 0 publications

Synthetic Wax Esters and Diesters from Crambe and Limnanthes Seed Oils

Synthetic Wax Esters and Diesters from Crambe and Limnanthes Seed Oils

Heterogeneous Catalysis in Oleochemistry

Secondary products from high pressure hydrogenation of crambe oil

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